Intermolecular Electron-Transfer Catalyzed on Nanoparticle Surfaces

被引：8
|
作者：
Carver, Adrienne M. [1 ]
De, Mrinmoy [1 ]
Bayraktar, Halil [1 ]
Rana, Subinoy [1 ]
Rotello, Vincent M. [1 ,2 ]
Knapp, Michael J. [1 ,2 ]
机构：
[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
[2] Univ Massachusetts, Program Mol & Cellular Biol, Amherst, MA 01003 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 11期
关键词：
FUNCTIONALIZED GOLD NANOPARTICLES; CYTOCHROME-C; TRIS(1,10-PHENANTHROLINE)COBALT(III); COMPLEXES; PROTEINS; BINDING; DOCKING; RATES;
D O I：
10.1021/ja806064t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Surface-functionalized nanoparticles enhance the rate of electron transfer (ET) between Cyt c(Fe2+) and Co(phen)(3)(3+) by a factor of 10(5) through simultaneous electrostatic binding of an ET donor and acceptor.
引用
收藏
页码：3798 / +
页数：3
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