Properties of Fluids Composed of Polyelectrolyte and Double-Chain Anionic Surfactant: Branched Polyethyleneimine and Sodium bis(2-ethylhexyl) Sulfosuccinate

被引:2
|
作者
Song, Shili [1 ]
Qian, Yuhua [1 ]
Wu, Qiuhua [1 ]
Fu, Peng [1 ]
Wang, Zhen [1 ]
机构
[1] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
基金
中国国家自然科学基金;
关键词
AOT; polyelectrolyte; polyethyleneimine; surfactant; DODECYL-SULFATE; IONIC SURFACTANTS; CHARGE-DENSITY; POLY(ETHYLENE IMINE); DELIVERY-SYSTEMS; LIGHT-SCATTERING; AQUEOUS-SOLUTION; LAMELLAR PHASE; WATER; COMPLEXES;
D O I
10.1080/01932691.2013.860034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties of fluids composed of branched polyethyleneimine (PEI) and sodium bis (2-ethylhexyl) sulfosuccinate (AOT) were investigated by steady-state fluorescence, dynamic light scattering, turbidity, conductivity, and pH measurements. Light scattering studies show that addition of PEI into AOT solution can significantly decrease the aggregate size of AOT, however, the aggregate volume of AOT/PEI complexes slightly changes with the [AOT] or [PEI]. H-1 NMR spectroscopy measurements show the line shape and chemical shifts of the protons around the head of AOT severely change with increase of [PEI] or [AOT]. It indicates that the interaction of AOT and PEI mainly occurs around the head of AOT.
引用
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页码:1449 / 1459
页数:11
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