Suzuki-Miyaura Micellar Cross-Coupling in Water, at Room Temperature, and under Aerobic Atmosphere

被引：62
|
作者：
Mattiello, Sara [1 ]
Rooney, Myles [1 ]
Sanzone, Alessandro [1 ]
Brazzo, Paolo [1 ]
Sassi, Mauro [1 ]
Beverina, Luca [1 ]
机构：
[1] Univ Milano Bicocca, Dept Mat Sci, Via R Cozzi 55, I-20125 Milan, Italy
来源：
ORGANIC LETTERS | 2017年 / 19卷 / 03期
关键词：
ORGANIC PHOTOVOLTAICS; UP-CONVERSION; CATALYSIS; SURFACTANT; MOLECULES; CHEMISTRY;
D O I：
10.1021/acs.orglett.6b03817
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recently, oxygen-equilibrated water solutions of Kolliphor EL, a well-known surfactant, have been seen to form nanomicelles with oxygen-free cores. This has prompted the successful testing of the core environment as a green medium for palladium-catalyzed Suzuki-Miyaura cross couplings. The versatility of these conditions is endorsed by several examples, including the synthesis of relevant molecular semiconductors. The reaction medium can also be recycled, opening the way for an extremely easy and green chemistry compliant methodology.
引用
收藏
页码：654 / 657
页数：4
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