Spectral investigation and structural characterization of Dibenzalacetone: β-Cyclodextrin inclusion complex

被引：34

作者：

Periasamy, R. ^{[1
]}

Rajamohan, R. ^{[2
]}

Kothainayaki, S. ^{[1
]}

Sivakumar, K. ^{[3
]}

机构：

[1] Annamalai Univ, FEAT, Chem Sect, Annamalainagar 608002, Tamil Nadu, India

[2] SKP Inst Technol, Dept Chem, Tiruvannamalai 606611, India

[3] SCSVMV Univ, Fac Sci, Dept Chem, Kanchipuram 631561, Tamil Nadu, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1068卷

关键词：

1,5-Diphenyl-1,4-pentadien-3-one; beta-Cyclodextrin; Inclusion complex; Atomic force microscopy; Thermal analysis; Molecular docking; ROOM-TEMPERATURE PHOSPHORESCENCE; FLUORESCENCE; ENHANCEMENT; DERIVATIVES; BEHAVIOR;

D O I：

10.1016/j.molstruc.2014.04.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interaction of Dibenzalacetone (DBA) with beta-Cyclodextrin (beta-CD) producing an inclusion complex was carried out by co-precipitation method. The binding constant was determined using steady state and time-resolved fluorescence spectroscopy and the results suggested that the inclusion complex preferred 1:1 stoichiometry. The complex was characterized by UV-Visible, infrared spectroscopy (FT-IR), differential scanning calorimetry (DSC) and X-ray diffractometry (XRD). The morphological characteristics of the solid complex were analyzed by Scanning electron microscope (SEM) and Atomic force microscope (AFM). The structure of 1:1 inclusion complex of DBA with beta-CD is proposed. The Docking study reveals that this structure was found to be highly probable and energitically favorable model. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：155 / 163

页数：9

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