Electrochemical recovery of metals in deep eutectic solvents

被引:4
作者
Mendes, T. [1 ]
Nano, G. [1 ]
Magagnin, L. [1 ]
机构
[1] Politecn Milan, Dip Chim Mat & Ing Chim Giulio Natta, I-20131 Milan, Italy
来源
GREEN ELECTRODEPOSITION 3 | 2013年 / 53卷 / 19期
关键词
IONIC LIQUIDS; CHOLINE CHLORIDE;
D O I
10.1149/05319.0063ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ionic liquids have been subject of many researches in the electrodeposition area in the last decades. It is known that this kind of liquids show some advantages when compared to the traditional aqueous media. The electroplating industry traditionally uses aqueous solutions, because of the high solubility of metal salts, resulting in highly conducting solutions. In hydrometallurgy, aqueous acids or alkalis are predominantly used to dissolve the metal oxides, sulphides, or silicates and further metal recovery processes require strong compounds which can be hazardous for the environment. This work will discuss the use of ionic liquids as deep eutectic solvents as solution for metal recovery and how such solvents can be used for different metals from their mineral matrix.
引用
收藏
页码:63 / 67
页数:5
相关论文
共 8 条
[1]   Application of hole theory to define ionic liquids by their transport properties [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2007, 111 (18) :4910-4913
[2]   Solubility of metal oxides in deep eutectic solvents based on choline chloride [J].
Abbott, Andrew P. ;
Capper, Glen ;
Davies, David L. ;
McKenzie, Katy J. ;
Obi, Stephen U. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (04) :1280-1282
[3]   Deep eutectic solvents formed between choline chloride and carboxylic acids: Versatile alternatives to ionic liquids [J].
Abbott, AP ;
Boothby, D ;
Capper, G ;
Davies, DL ;
Rasheed, RK .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :9142-9147
[4]   Novel solvent properties of choline chloride/urea mixtures [J].
Abbott, AP ;
Capper, G ;
Davies, DL ;
Rasheed, RK ;
Tambyrajah, V .
CHEMICAL COMMUNICATIONS, 2003, (01) :70-71
[5]   Hydrophobic, highly conductive ambient-temperature molten salts [J].
Bonhote, P ;
Dias, AP ;
Papageorgiou, N ;
Kalyanasundaram, K ;
Gratzel, M .
INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178
[6]   Ionic liquids: solvent properties and organic reactivity [J].
Chiappe, C ;
Pieraccini, D .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 2005, 18 (04) :275-297
[7]   Comparative UV-Vis studies of uranyl chloride complex in two basic ambient-temperature melt systems: The observation of spectral and thermodynamic variations induced via hydrogen bonding [J].
Dai, S ;
Shin, YS ;
Toth, LM ;
Barnes, CE .
INORGANIC CHEMISTRY, 1997, 36 (21) :4900-4902
[8]  
ENDRES F, 2007, ELECTRODEPOSITION ME