Synthesis, spectroscopic characterization, and X-ray crystal structure of tris(trimethylsilyl)cyanurate

被引：2
作者：
El-Gamel, Nadia E. A. [1 ]
Brand, Joerg [2 ]
Kroke, Edwin [3 ]
机构：
[1] Cairo Univ, Fac Sci, Dept Chem, Giza 12613, Egypt
[2] Univ Konstanz, Dept Chem, D-78457 Constance, Germany
[3] Tech Univ Bergakad Freiberg, Inst Anorgan Chem, D-09596 Freiberg, Germany
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 08期
关键词：
S-triazine; Tri-s-triazine; FTIR and Raman spectra; NMR; Thermal behavior; X-ray crystal structure; TRI-S-TRIAZINE; CYANURIC ACID; DERIVATIVES; INTERMEDIATE; CHEMISTRY; POLYMERS;
D O I：
10.1080/00958970802499372
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Tris(trimethylsilyl)cyanurate, C12H27N3O3Si3 (1), has been synthesized and characterized by elemental analysis, IR, Raman, 13C and 29Si NMR, and thermogravimetric methods. The molecular and crystal structure has been determined by single crystal X-ray diffraction. This compound crystallized in space group P63/m (176), Z = 2 with a = 11.017(2), b = 11.017(2), c = 9.676(3) ; = 90, = 90, = 120. The geometry of the molecule is compared with tris(trimethylsilyl)cyamelurate.
引用
收藏
页码：1278 / 1284
页数：7
相关论文
共 51 条
[1]   A Wellsian 'three-dimensional' racemate: Eight interpenetrating, enantiomorphic (10,3)-a nets, four right- and four left-handed [J].
Abrahams, BF ;
Batten, SR ;
Hamit, H ;
Hoskins, BF ;
Robson, R .
CHEMICAL COMMUNICATIONS, 1996, (11) :1313-1314
[2]  
BAILEY DL, 1960, Patent No. 2949434
[3]   TRIAZINE-BASED POLYMERS .2. SYNTHESIS AND CHARACTERIZATION OF POLYETHERS [J].
BRAUN, D ;
MOST, D ;
ZISER, T .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1994, 221 :187-205
[4]   Synthesis, structural characterization and antitumor activity of novel 2,4-diamino-1,3,5-triazine derivatives [J].
Brzozowski, Z ;
Saczewski, F ;
Gdaniec, M .
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2000, 35 (12) :1053-1064
[5]   An aromatic anion receptor:: Anion-π interactions do exist [J].
de Hoog, P ;
Gamez, P ;
Mutikainen, H ;
Turpeinen, U ;
Reedijk, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (43) :5815-5817
[6]  
DERGUNOV YI, 1976, ZH OBSHCH KHIM+, V46, P1573
[7]   The tautomeric forms of cyameluric acid derivatives [J].
El-Gamel, Nadia E. A. ;
Seyfarth, Lena ;
Wagler, Joerg ;
Ehrenberg, Helmut ;
Schwarz, Marcus ;
Senker, Juergen ;
Kroke, Edwin .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (04) :1158-1173
[8]   s-triazine and tri-s-triazine based organic-inorganic hybrid gels prepared from chlorosilanes by exchange reactions [J].
El-Gamel, Nadia E. A. ;
Schwarz, Marcus ;
Brendler, Erica ;
Kroke, Edwin .
CHEMICAL COMMUNICATIONS, 2006, (45) :4741-4743
[9]   Utility and synthetic uses of Mannich reaction: An efficient route for synthesis of thiadiazino-[1,3,5][3,2-a]benzimidazoles [J].
El-Wareth, A ;
Sarhan, AO ;
Abdel-Hafez, SH ;
El-Sherief, H ;
Aboel-Fadl, T .
SYNTHETIC COMMUNICATIONS, 2006, 36 (08) :987-996
[10]   POLYCYANATE ESTERS - SCIENCE AND APPLICATIONS [J].
FANG, T ;
SHIMP, DA .
PROGRESS IN POLYMER SCIENCE, 1995, 20 (01) :61-118
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