Macroscopic Supramolecular Assembly of Rigid Building Blocks Through a Flexible Spacing Coating

被引：106
作者：
Cheng, Mengjiao [1 ,2 ]
Shi, Feng [1 ,2 ]
Li, Jianshu [3 ]
Lin, Zaifu [3 ]
Jiang, Chao [1 ,2 ]
Xiao, Meng [1 ,2 ]
Zhang, Liqun [1 ,2 ]
Yang, Wantai [1 ,2 ]
Nishi, Toshio [4 ]
机构：
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymer, Minist Educ, Beijing 100029, Peoples R China
[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China
[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan
来源：
ADVANCED MATERIALS | 2014年 / 26卷 / 19期
关键词：
supramolecular assembly; self-assembly; macroscopic supramolecular assembly; flexible spacing coating; multivalency; BETA-CYCLODEXTRIN; THERMODYNAMICS; DESIGN;
D O I：
10.1002/adma.201305177
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：3009 / 3013
页数：5
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