Macroscopic Supramolecular Assembly of Rigid Building Blocks Through a Flexible Spacing Coating

被引：107

作者：

Cheng, Mengjiao ^{[1
,2
]}

Shi, Feng ^{[1
,2
]}

Li, Jianshu ^{[3
]}

Lin, Zaifu ^{[3
]}

Jiang, Chao ^{[1
,2
]}

Xiao, Meng ^{[1
,2
]}

Zhang, Liqun ^{[1
,2
]}

Yang, Wantai ^{[1
,2
]}

Nishi, Toshio ^{[4
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymer, Minist Educ, Beijing 100029, Peoples R China

[3] Sichuan Univ, Coll Polymer Sci & Engn, Chengdu 610065, Peoples R China

[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

ADVANCED MATERIALS | 2014年 / 26卷 / 19期

关键词：

supramolecular assembly; self-assembly; macroscopic supramolecular assembly; flexible spacing coating; multivalency; BETA-CYCLODEXTRIN; THERMODYNAMICS; DESIGN;

D O I：

10.1002/adma.201305177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Macroscopic supramolecular assembly is a promising method for manufacturing macroscopic, ordered structures for tissue-engineering scaffolds. A flexible spacing coating is shown to overcome undesired surface and size effects and to enable assembly of macroscopic cubes with host/guest groups. The assembled pairs disassembled upon introduction of competitive guest molecules, thereby demonstrating a multivalent assembly mechanism. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3009 / 3013

页数：5

共 35 条

[1]

[Anonymous], 1999, ANGEW CHEM INT ED, V38, P3078

[2]

[Anonymous], 1988, ANGEW CHEM INT ED, V27, P89

[3]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P11378

[4]

[Anonymous], 2011, ANGEW CHEM-GER EDIT

[5]

[Anonymous], 2010, ANGEW CHEM

[6]

[Anonymous], 1988, ANGEW CHEM INT ED EN, V27, P113

[7]

[Anonymous], 2010, ANGEW CHEM INT ED, V49, P6881

[8]

[Anonymous], 2012, ANGEW CHEM, DOI DOI 10.1002/ANGE.201201114

[9] Molecule-mimetic chemistry and mesoscale self-assembly [J].

Bowden, NB ;

Weck, M ;

Choi, IS ;

Whitesides, GM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (03) :231-238

[10] Design and self-assembly of open, regular, 3D mesostructures [J].

Breen, TL ;

Tien, J ;

Oliver, SRJ ;

Hadzic, T ;

Whitesides, GM .

SCIENCE, 1999, 284 (5416) :948-951

← 1 2 3 4 →