New chiral sultam auxiliaries: preparation and their application in asymmetric Diels-Alder reactions

被引：33

作者：

Chan, WH ^{[1
]}

Lee, AWM ^{[1
]}

Jiang, LS ^{[1
]}

Mak, TCW ^{[1
]}

机构：

[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHATIN,HONG KONG

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 15期

关键词：

D O I：

10.1016/S0957-4166(97)00307-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure sultams (+)-4 and (-)-4 were synthesized from tricyclic sultone 1 via a four-step reaction sequence. Their uses as new chiral auxiliaries in asymmetric Diels-Alder reactions with diastereoselectivity up to 94:6 are presented. (C) 1997 Elsevier Science Ltd.

引用

页码：2501 / 2504

页数：4

共 10 条

[1]

GAWLEY RE, 1996, PRINCIPLES ASYMMETRI, P267

[2]

HELMCHEN G, 1986, MODERN SYNTHETIC MET, V4, P262

[3] TOTAL SYNTHESES OF SANDALWOOD FRAGRANCES - (Z)-BETA-SANTALOL AND (E)-BETA-SANTALOL AND THEIR ENANTIOMERS, ENT-BETA-SANTALENE [J].