Polydimethylphosphazene (PDMP) has been tested for the first time to fabricate a water resistive humidity sensor. The device consists of a PDMP free-standing membrane coated on both sides with gold electrodes forming a parallel capacitor. A change in electrical capacitance and resistance of about three orders of magnitude was observed with increasing relative humidity (RH) from 0% to 100%. The results show that polyphosphazenes are promising materials for resistive and capacitive sensors in the complete range of RH.