Chemical design of a smart chitosan-polypyrrole-magnetite nanocomposite toward efficient water treatment

被引:56
作者
Ayad, Mohamad [1 ]
Salahuddin, Nehal [1 ]
Fayed, Aya [1 ]
Bastakoti, Bishnu Prasad [2 ]
Suzuki, Norihiro [3 ]
Yamauchi, Yusuke [2 ,4 ]
机构
[1] Tanta Univ, Fac Sci, Dept Chem, Tanta 31527, Egypt
[2] Natl Inst Mat Sci, World Premier Int WPI Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan
[3] Natl Inst Mat Sci, Int Ctr Young Scientists, Tsukuba, Ibaraki 3050047, Japan
[4] Waseda Univ, Fac Sci & Engn, Shinjuku Ku, Tokyo 1698555, Japan
关键词
FUNCTIONALIZED MESOPOROUS SILICA; AEROSOL-ASSISTED SYNTHESIS; IRON-OXIDE; AQUEOUS-SOLUTION; FE3O4; NANOPARTICLES; REMOVAL; ADSORPTION; COMPOSITES; POLYANILINE; DYE;
D O I
10.1039/c4cp03062a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A magnetic chitosan polypyrrole magnetite (Cs-PPy-Fe3O4) nanocomposite is prepared in a simple one-step method via in situ chemical polymerization of pyrrole using anhydrous FeCl3 as an oxidant in the presence of Cs. Magnetic Fe3O4 nanoparticles of size in the range of 10-20 nm are successfully introduced into the Cs-PPy matrix. Adsorption of an anionic dye (acid green 25, AG) from aqueous solution into the Cs-PPy-Fe3O4 nanocomposite is investigated. The nanocomposite exhibits high adsorption capacity compared to PPy and Cs themselves. After the adsorption, the Cs-PPy-Fe3O4 nanocomposite is easily separated from the reaction solution using an external magnet, which is very useful for practical applications.
引用
收藏
页码:21812 / 21819
页数:8
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