A bis-cyclometalated iridium complex as a benchmark sensitizer for efficient visible-to-UV photon upconversion

被引：78
作者：
Duan, Pengfei [1 ]
Yanai, Nobuhiro [1 ]
Kimizuka, Nobuo [1 ]
机构：
[1] Kyushu Univ, CMS, Grad Sch Engn, Dept Chem & Biochem,Nishi Ku, Fukuoka 8190395, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 86期
关键词：
TRIPLET-TRIPLET ANNIHILATION; LOW-POWER; EXCITATION; PYRENE; LIGHT; BLUE;
D O I：
10.1039/c4cc05718j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
To resolve the biggest problemin visible-to-UV photon upconversion based on sensitized triplet-triplet annihilation-the quenching of upconverted fluorescence by sensitizers-we discovered a superior sensitizer with less UV absorption intensity that enables highly efficient, low-power (0.78 mW cm(-2)) visible-to-UV upconversion.
引用
收藏
页码：13111 / 13113
页数：3
相关论文
共 27 条
  • [1] [Anonymous], 1991, MODERN MOL PHOTOCHEM
  • [2] Blue-green up-conversion:: Noncoherent excitation by NIR light
    Baluschev, Stanislav
    Yakutkin, Vladimir
    Miteva, Tzenka
    Avlasevich, Yuri
    Chernov, Sergei
    Aleshchenkov, Sergei
    Nelles, Gabriele
    Cheprakov, Andrei
    Yasuda, Akio
    Muellen, Klaus
    Wegner, Gerhard
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (40) : 7693 - 7696
  • [3] Ultrabright oxygen optodes based on cyclometalated lridium(III) coumarin complexes
    Borisov, Sergey M.
    Klimant, Ingo
    [J]. ANALYTICAL CHEMISTRY, 2007, 79 (19) : 7501 - 7509
  • [4] Energy Up-Conversion by Low-Power Excitation: New Applications of an Old Concept
    Ceroni, Paola
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (35) : 9560 - 9564
  • [5] On the efficiency limit of triplet-triplet annihilation for photochemical upconversion
    Cheng, Yuen Yap
    Khoury, Tony
    Clady, Raphael G. C. R.
    Tayebjee, Murad J. Y.
    Ekins-Daukes, N. J.
    Crossley, Maxwell J.
    Schmidt, Timothy W.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (01) : 66 - 71
  • [6] Annihilation Limit of a Visible-to-UV Photon Upconversion Composition Ascertained from Transient Absorption Kinetics
    Deng, Fan
    Blumhoff, Joerg
    Castellano, Felix N.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (21) : 4412 - 4419
  • [7] Photon Upconverting Liquids: Matrix-Free Molecular Upconversion Systems Functioning in Air
    Duan, Pengfei
    Yanai, Nobuhiro
    Kimizuka, Nobuo
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (51) : 19056 - 19059
  • [8] Diarylpyrenes vs. diaryltetrahydropyrenes: Crystal structures, fluorescence, and upconversion photochemistry
    El-Ballouli, Ala'a O.
    Khnayzer, Rony S.
    Khalife, Jihane C.
    Fonari, Alexandr
    Hallal, Kassem M.
    Timofeeva, Tatiana V.
    Patra, Digambara
    Castellano, Felix N.
    Wex, Brigitte
    Kaafarani, Bilal R.
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2013, 272 : 49 - 57
  • [9] Triplet-triplet annihilation photon-upconversion: towards solar energy applications
    Gray, Victor
    Dzebo, Damir
    Abrahamsson, Maria
    Albinsson, Bo
    Moth-Poulsen, Kasper
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (22) : 10345 - 10352
  • [10] Getting to the (Square) Root of the Problem: How to Make Noncoherent Pumped Upconversion Linear
    Haefele, Alexandre
    Blumhoff, Joerg
    Khnayzer, Rony S.
    Castellano, Felix N.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (03): : 299 - 303
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