The first example of tungsten-based carbene generation from WC16 and atomic carbon and its use in olefin metathesis

被引：5

作者：

Duz, Bulent ^{[1
]}

Yuksel, Dilek ^{[1
]}

Ece, Abdulilah ^{[1
]}

Sevin, Fatma ^{[1
]}

机构：

[1] Hacettepe Univ, Dept Chem, TR-06532 Ankara, Turkey

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 29期

关键词：

carbon arc; olefin metathesis; WC1(6); DFT;

D O I：

10.1016/j.tetlet.2006.05.054

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe a new route for the synthesis of tungsten-based carbenes generated by the reaction of WCl6 with atomic carbon in a carbon arc reactor. The active species formed under these conditions, [W] = CCl2, was found to catalyze olefin metathesis reactions of 1-octene, 2-octene and 1-heptene. We also evaluated the mechanism of formation of [W] = CCl2 within the WCl6/C system at the DFT level. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：5167 / 5170

页数：4

共 21 条

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