The millimeter-wave spectrum of chlorine nitrate (ClONO2):: The 2νg and ν7 vibrational states

被引:10
作者
Butler, RAH [1 ]
Albert, S
Petkie, DT
Helminger, P
De Lucia, FC
机构
[1] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA
[2] Swiss Fed Inst Technol, Phys Chem Lab, CH-8092 Zurich, Switzerland
[3] Ohio No Univ, Dept Phys, Ada, OH 45810 USA
[4] Univ S Alabama, Dept Phys, Mobile, AL 36688 USA
关键词
chlorine nitrate; nu(7); 2 nu(9); ClONO2; millimeter; spectra; spectroscopy;
D O I
10.1006/jmsp.2002.8517
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Chlorine nitrate is a molecule of interest in atmospheric studies because of its role as a reservoir species, removing both chlorine and nitrogen species from catalytic cycles of ozone destruction. The ground and nu(9) vibrational states have been previously studied in the millimeter and submillimeter spectral regions. We have now recorded and analyzed the next states that are lowest in energy, the coupled 2nu(9)/nu(7) dyad, from 128 through 355 GHz using a fast scan submillimeter spectroscopic technique system. (C) 2002 Elsevier Science (USA).
引用
收藏
页码:8 / 14
页数:7
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