Bi(TFA)3 immobilized in [nbpy]FeCl4:: An efficient catalyst system for the one-pot synthesis of 4,6-diarylpyrimidin-2(1H)-ones

被引:46
作者
Khosropour, Ahmad R. [1 ]
Mohammadpoor-Baltork, Iraj
Ghorbankhani, Hamid
机构
[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran
[2] Isfahan Univ, Dept Chem, Esfahan 81746 73441, Iran
关键词
bismuth(III) trifluoroacetate; nbpy]FeCl4; 4,6-diarylpyrimidin-2(1H) -ones; one-pot synthesis;
D O I
10.1016/j.catcom.2006.02.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Bismuth(III) trifluoroacetate immobilized on [nbpy]FeCl4 was found to be an efficient and low toxic catalytic system for the one-pot synthesis of 4,6-diarylpyrimidin-2(1H)-ones. This procedure is very easy, rapid and high yielding reaction for the synthesis of the pyrimidin-2(1H)-one derivatives. The catalyst exhibited remarkable reactivity and it is reusable. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:713 / 716
页数:4
相关论文
共 31 条
  • [1] 6-[1-(2,6-difluorophenyl)ethyl]pyrimidinones antagonize cell proliferation and induce cell differentiation by inhibiting (a nontelomeric) endogenous reverse transcriptase
    Bartolini, S
    Mai, A
    Artico, M
    Paesano, N
    Rotili, D
    Spadafora, C
    Sbardella, G
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 2005, 48 (22) : 6776 - 6778
  • [2] Green Chemistry: challenges and opportunities
    Clark, JH
    [J]. GREEN CHEMISTRY, 1999, 1 (01) : 1 - 8
  • [3] Ionic liquid (molten salt) phase organometallic catalysis
    Dupont, J
    de Souza, RF
    Suarez, PAZ
    [J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3667 - 3691
  • [4] Discovery of a magnetic ionic liquid [bmim]FeCl4
    Hayashi, S
    Hamaguchi, HO
    [J]. CHEMISTRY LETTERS, 2004, 33 (12) : 1590 - 1591
  • [5] [Cu(I)(bpp)]BF4:: the first extended coordination network prepared solvothermally in an ionic liquid solvent
    Jin, K
    Huang, XY
    Pang, L
    Li, J
    Appel, A
    Wherland, S
    [J]. CHEMICAL COMMUNICATIONS, 2002, (23) : 2872 - 2873
  • [6] KARINA S, 2002, J CHEM SOC P1, P774
  • [7] A novel enamination of β-dicarbonyl compounds catalyzed by Bi(TFA)3 immobilized on molten TBAB
    Khodaei, MM
    Khosropour, A
    Kookhazadeh, M
    [J]. CANADIAN JOURNAL OF CHEMISTRY, 2005, 83 (03) : 209 - 212
  • [8] Bi(NO3)3•5H2O-TBAF as an efficient reagent for in situ oxidation:: Dihydropyrimidinone formation from benzyl halides
    Khodaei, MM
    Khosropour, AR
    Jowkar, M
    [J]. SYNTHESIS-STUTTGART, 2005, (08): : 1301 - 1304
  • [9] Enamination of β-dicarbonyl compounds catalyzed by CeCl3•7H2O at ambient conditions:: Ionic liquid and solvent-free media
    Khodaei, MM
    Khosropour, AR
    Kookhazadeh, M
    [J]. SYNLETT, 2004, (11) : 1980 - 1984
  • [10] A powerful, practical and chemoselective synthesis of 2-anilinoalkanols catalyzed by Bi(TFA)3 or Bi(OTf)3 in the presence of molten TBAB
    Khodaei, MM
    Khosropour, AR
    Ghozati, K
    [J]. TETRAHEDRON LETTERS, 2004, 45 (17) : 3525 - 3529