Marinite Li2M(SO4)2 (M = Co, Fe, Mn) and Li1Fe(SO4)2: Model Compounds for Super-Super-Exchange Magnetic Interactions

被引：47

作者：

Reynaud, Marine ^{[1
]}

Rousse, Gwenaelle ^{[2
]}

Chotard, Jean-Noel ^{[1
]}

Rodriguez-Carvajal, Juan ^{[3
]}

Tarascon, Jean-Marie ^{[1
]}

机构：

[1] Univ Picardie Jules Verne, CNRS, UMR 7314, LRCS, F-80039 Amiens, France

[2] Univ Paris 06, CNRS, IMPMC, UMR 7590, F-75252 Paris 05, France

[3] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 18期

关键词：

NEUTRON-DIFFRACTION TECHNIQUES; POSITIVE-ELECTRODE MATERIAL; TRIPLITE STRUCTURE; CRYSTAL-STRUCTURE; ION BATTERIES; GROUND-STATE; NUCLEAR; NI; LI; SUSCEPTIBILITY;

D O I：

10.1021/ic401280e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New materials initially designed for battery electrodes are often of interest for magnetic study, because their chemical compositions include 3d transition metals. We report here on the magnetic properties of marinite phases Li2M(SO4)(2) (M = Fe, Co, Mn) and Li1Fe(SO4)(2), which all order antiferromagnetically at low temperature. From neutron powder diffraction, we propose a model for their ground-state magnetic structures. The magnetism of marinite Li2M(SO4)(2) compounds unambiguously results from super-super-exchange interactions; therefore, these materials can be considered as a model case for which the Goodenough-Kanamori-Anderson rules can be tested.

引用

页码：10456 / 10466

页数：11

共 50 条

[41] THE CRYSTAL-STRUCTURES OF KIESERITE-TYPE COMPOUNDS .1. CRYSTAL-STRUCTURES OF ME(II)SO4 H2O (ME = MN,FE,CO,NI,ZN) [J].

WILDNER, M ;

GIESTER, G .

NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 1991, (07) :296-306

[42] Structural features of a new [Fe(nicotinamide)2(H2O)4]•[Fe(H2O)6]• (SO4)2•2H2O complex [J].

Çakir, S ;

Biçer, E ;

Aoki, K ;

Coskun, E .

CRYSTAL RESEARCH AND TECHNOLOGY, 2006, 41 (03) :314-320

[43] Li2Cu2O(SO4)2: a Possible Electrode for Sustainable Li-Based Batteries Showing a 4.7 V Redox Activity vs Li+/Li0 [J].

Sun, Meiling ;

Rousse, Gwenaelle ;

Abakumov, Artem M. ;

Saubanere, Matthieu ;

Doublet, Marie-Liesse ;

Rodriguez-Carvajal, Juan ;

Van Tendeloo, Gustaaf ;

Tarascon, Jean-Marie .

CHEMISTRY OF MATERIALS, 2015, 27 (08) :3077-3087

[44] Further New Borosulfates: Synthesis, Crystal Structure, and Vibrational Spectra of A[B(SO4)2] (A = Na, K, NH4) and the Crystal Structures of Li5[B(SO4)4] and NH4[B(S2O7)2] [J].

Daub, Michael ;

Hoeppe, Henning A. ;

Hillebrecht, Harald .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (14) :2914-2921

[45] Structure retinement and chemical analysis of Cs3Li(DSO4)4, formerly 'Cs1.5Li1.5D(SO4)2' [J].

Klooster, WT ;

Piltz, RO ;

Uda, T ;

Haile, SM .

JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (01) :274-280

[46] Understanding 6Li MAS NMR spectra of Li2MSiO4 materials (M=Mn, Fe, Zn) [J].

Mali, Gregor ;

Rangus, Mojca ;

Sirisopanaporn, Chutchamon ;

Dominko, Robert .

SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2012, 42 :33-41

[47] SolvothermalSynthesisandCrystalStructureofaNovelInorganic-OrganicHybridMaterial,Fe2O（OH）(C5H4NCOO)SO4 [J].

郭洪猷 ;

李增和 ;

李秀艳 ;

张长远 ;

王如骥 .

ChineseJournalofChemistry, 2003, (04) :466-470+364

[48] CRYSTAL STRUCTURE OF FLUOROSULFATE COMPLEX COMPOUNDS OF INDIUM(III) M2[InF3(SO4)H2O] (M = K, NH4) [J].

Davidovich, R. L. ;

Logvinova, V. B. ;

Tkachev, V. V. ;

Shilov, G. V. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (01) :97-101

[49] Crystal structure of fluorosulfate complex compounds of indium(III) M2[InF3(SO4)H2O] (M = K, NH4) [J].

R. L. Davidovich ;

V. B. Logvinova ;

V. V. Tkachev ;

G. V. Shilov .

Journal of Structural Chemistry, 2017, 58 :97-101

[50] Preparation and X-ray diffraction study of phosphate sulfates M2MgTi(SO4)(PO4)2 [J].

Kanunov, A. E. ;

Asabina, E. A. ;

Orlova, A. I. .

RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2016, 86 (01) :18-25

← 1 2 3 4 5 →