A Facile and Efficient Preparation of Pillararenes and a Pillarquinone

被引：637

作者：

Cao, Derong ^{[1
]}

Kou, Yuhui ^{[1
]}

Liang, Jianquan ^{[1
]}

Chen, Zhizhao ^{[1
]}

Wang, Lingyun ^{[1
]}

Meier, Herbert ^{[2
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China

[2] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55099 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 51期

基金：

中国国家自然科学基金;

关键词：

arenes; cyclooligomers; host-guest chemistry; ipso-alkylation; quinones; CALIXARENES; CALIXPYRROLES; COMPLEXATION; CATALYSIS; NANOTUBES;

D O I：

10.1002/anie.200904765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ring around the roses: The ipso substitution of benzene rings makes a simple and efficient synthesis of pillar[n]arenes (n=5, 6) possible. Pillar[6]arenes (see picture) and pillar[5]quinone, an oxidation product of pillar[5]arene, are novel highly promising host systems for hostlguest chemistry. © 2009 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：9721 / 9723

页数：3

共 27 条

[1]

Ananchenko G. S., 2008, ANGEW CHEM, V120, P5698

[2] A channel-free soft-walled capsular calixarene solid for gas adsorption [J].

Ananchenko, Gennady S. ;

Moudrakovski, Igor L. ;

Coleman, Anthony W. ;

Ripmeester, John A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (30) :5616-5618

[3]

[Anonymous], 2009, Angew. Chem.

[4] PURIFICATION OF C-60 AND C-70 BY SELECTIVE COMPLEXATION WITH CALIXARENES [J].

ATWOOD, JL ;

KOUTSANTONIS, GA ;

RASTON, CL .

NATURE, 1994, 368 (6468) :229-231

[5] Mononuclear and dinuclear molybdenum and tungsten complexes of p-tert-butyltetrathiacalix[4]arene and p-tert-butyltetrasulfonylcalix[4]arene:: Facile cleavage of the calixarene ligand framework by nickel [J].

Buccella, Daniela ;

Parkin, Gerard .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (27) :8617-+

[6] Calix[5]arene: a versatile sublimate that displays gas sorption properties [J].

Dalgarno, Scott J. ;

Tian, Jian ;

Warren, John E. ;

Clark, Thomas E. ;

Makha, Mohamed ;

Raston, Colin L. ;

Atwood, Jerry L. .

CHEMICAL COMMUNICATIONS, 2007, (46) :4848-4850

[7] Calixpyrroles II [J].

Gale, PA ;

Anzenbacher, P ;

Sessler, JL .

COORDINATION CHEMISTRY REVIEWS, 2001, 222 :57-102

[8] (1.1.1.1.1)PARACYCLOPHANE AND (1.1.1.1.1.1)PARACYCLOPHANE [J].

GRIBBLE, GW ;

NUTAITIS, CF .

TETRAHEDRON LETTERS, 1985, 26 (49) :6023-6026

[9] CALIXARENES .4. THE SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF THE CALIXARENES FROM PARA-TERT-BUTYLPHENOL [J].

GUTSCHE, CD ;

DHAWAN, B ;

NO, KH ;

MUTHUKRISHNAN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (13) :3782-3792

[10] The Use of Calixarenes in Metal-Based Catalysis [J].

Homden, Damien M. ;

Redshaw, Carl .

CHEMICAL REVIEWS, 2008, 108 (12) :5086-5130

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