Carbon nitride supported AgPd alloy nanocatalysts for dehydrogenation of formic acid under visible light

被引：51
作者：
Xiao, Liping [1 ,2 ]
Jun, Young-Si [2 ,3 ]
Wu, Binghui [2 ,4 ]
Liu, Deyu [2 ]
Chuong, Tracy T. [2 ]
Fan, Jie [1 ]
Stucky, Galen D. [2 ,4 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Chonnam Natl Univ, Sch Appl Chem Engn, 77 Yongbong Ro, Gwangju 500757, South Korea
[4] Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, Xiamen 361005, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2017年 / 5卷 / 14期
基金：
美国国家科学基金会;
关键词：
MACRORETICULAR BASIC RESIN; HYDROGEN-STORAGE MATERIALS; ROOM-TEMPERATURE; EFFICIENT CATALYST; AMBIENT CONDITIONS; NANOPARTICLES; DECOMPOSITION; PD; GENERATION; NANOCRYSTALS;
D O I：
10.1039/c7ta01039g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
AgPd alloy nanoparticles deposited on carbon nitride have been synthesized by a facile one-step reduction method and exhibit high catalytic activity at near room temperature (30 degrees C) for formic acid dehydrogenation, both under visible light and in darkness. The study proves that using the synergistic combination of alloying effects and metal-support interactions greatly enhances the catalytic activity of Pd-based nanocatalysts for hydrogen generation.
引用
收藏
页码：6382 / 6387
页数：6
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