Carbon nitride supported AgPd alloy nanocatalysts for dehydrogenation of formic acid under visible light

被引:51
作者
Xiao, Liping [1 ,2 ]
Jun, Young-Si [2 ,3 ]
Wu, Binghui [2 ,4 ]
Liu, Deyu [2 ]
Chuong, Tracy T. [2 ]
Fan, Jie [1 ]
Stucky, Galen D. [2 ,4 ]
机构
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Zhejiang, Peoples R China
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Chonnam Natl Univ, Sch Appl Chem Engn, 77 Yongbong Ro, Gwangju 500757, South Korea
[4] Xiamen Univ, Collaborat Innovat Ctr Chem Energy Mat, Xiamen 361005, Peoples R China
基金
美国国家科学基金会;
关键词
MACRORETICULAR BASIC RESIN; HYDROGEN-STORAGE MATERIALS; ROOM-TEMPERATURE; EFFICIENT CATALYST; AMBIENT CONDITIONS; NANOPARTICLES; DECOMPOSITION; PD; GENERATION; NANOCRYSTALS;
D O I
10.1039/c7ta01039g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
AgPd alloy nanoparticles deposited on carbon nitride have been synthesized by a facile one-step reduction method and exhibit high catalytic activity at near room temperature (30 degrees C) for formic acid dehydrogenation, both under visible light and in darkness. The study proves that using the synergistic combination of alloying effects and metal-support interactions greatly enhances the catalytic activity of Pd-based nanocatalysts for hydrogen generation.
引用
收藏
页码:6382 / 6387
页数:6
相关论文
共 53 条
  • [1] RADIOLYSIS AND PHOTOLYSIS OF AQUEOUS FORMIC ACID - CARBON MONOXIDE FORMATION
    ADAMS, GE
    HART, EJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (21) : 3994 - &
  • [2] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions
    Bi, Qng-Yuan
    Du, Xian-Long
    Liu, Yong-Mei
    Cao, Yong
    He, He-Yong
    Fan, Kang-Nian
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) : 8926 - 8933
  • [3] Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst
    Boddien, Albert
    Mellmann, Doerthe
    Gaertner, Felix
    Jackstell, Ralf
    Junge, Henrik
    Dyson, Paul J.
    Laurenczy, Gabor
    Ludwig, Ralf
    Beller, Matthias
    [J]. SCIENCE, 2011, 333 (6050) : 1733 - 1736
  • [4] Probing the interaction of poly( vinylpyrrolidone) with platinum nanocrystals by UV-Raman and FTIR
    Borodko, Yuri
    Habas, Susan E.
    Koebel, Matthias
    Yang, Peidong
    Frei, Heinz
    Somorjai, Gabor A.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (46) : 23052 - 23059
  • [5] Highly Efficient Dehydrogenation of Formic Acid over a Palladium-Nanoparticle-Based Mott-Schottky Photocatalyst
    Cai, Yi-Yu
    Li, Xin-Hao
    Zhang, Ya-Nan
    Wei, Xiao
    Wang, Kai-Xue
    Chen, Jie-Sheng
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (45) : 11822 - 11825
  • [6] g-C3N4-Based Photocatalysts for Hydrogen Generation
    Cao, Shaowen
    Yu, Jiaguo
    [J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (12): : 2101 - 2107
  • [7] Semiconductor-based Photocatalytic Hydrogen Generation
    Chen, Xiaobo
    Shen, Shaohua
    Guo, Liejin
    Mao, Samuel S.
    [J]. CHEMICAL REVIEWS, 2010, 110 (11) : 6503 - 6570
  • [8] Support effect in high activity gold catalysts for CO oxidation
    Comotti, M
    Li, WC
    Spliethoff, B
    Schüth, F
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) : 917 - 924
  • [9] Mesoporous Ti0.5Cr0.5N Supported PdAg Nanoalloy as Highly Active and Stable Catalysts for the Electrooxidation of Formic Acid and Methanol
    Cui, Zhiming
    Yang, Minghui
    DiSalvo, Francis J.
    [J]. ACS NANO, 2014, 8 (06) : 6106 - 6113
  • [10] Gold Nanoparticles Embedded in a Mesoporous Carbon Nitride Stabilizer for Highly Efficient Three-Component Coupling Reaction
    Datta, K. K. R.
    Reddy, B. V. Subba
    Ariga, Katsuhiko
    Vinu, Ajayan
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (34) : 5961 - 5965