Transients in RAFT miniemulsion polymerization in CSTR trains

被引：13
|
作者：
Qi, Genggeng [1 ]
Jones, Christopher W. [1 ]
Schork, Joseph F. [1 ]
机构：
[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2006年 / 45卷 / 21期
关键词：
D O I：
10.1021/ie060293q
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Potential factors contributing to previously observed unexpected transients during miniemulsion polymerization in continuously stirred tank reactor (CSTR) trains are examined. Possibilities from equipment design and operation are first evaluated, and with a slightly modified CSTR train, no significant transients are observed. Causes for the transients associated with the polymerization mechanism are also considered and ruled out by careful analysis. Steady state in a reversible addition-fragmentation transfer CSTR train is achieved.
引用
收藏
页码：7084 / 7089
页数：6
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