On the formation of framework indium sulfides

被引：96
作者：
Cahill, CL
Parise, JB
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA
[2] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 09期
关键词：
D O I：
10.1039/a909005c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Novel layered and open framework indium sulfide organic/inorganic hybrid materials have been synthesized via hydro- and solvo-thermal techniques. Considerable structural diversity within this family of compounds is realized through a variety of structural building units. DEA-InS-SB1 and -SB2 (both [(CH3CH2)(2)NH2](6)In10S18) consist of corner linked In10S20 supertetrahedra; DPA-InS-ML ([C6H16N](4)In4S10H4) contains isolated In4S10 thioanions, while TMDP-InS-SB4 ([C13H14N2](4)In9S17) has a layered structure containing linked In9S20 double adamantane clusters. Factors governing the formation of the structural building units (in the presence of amines) and their subsequent template mediated assembly are discussed with respect to previously reported and novel structure types.
引用
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页码：1475 / 1482
页数：8
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