A porous 3D heterometal-organic framework containing both lanthanide and high-spin Fe(II) ions

被引:136
作者
Zhao, Bin [1 ]
Chen, Xiao-Yan [1 ]
Chen, Zhi [1 ]
Shi, Wei [1 ]
Cheng, Peng [1 ]
Yan, Shi-Ping [1 ]
Liao, Dai-Zheng [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
COORDINATION POLYMERS; COMPLEXES; LUMINESCENCE; ARRAYS;
D O I
10.1039/b821496d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first porous 3D [Ln-Fe] heterometal-organic frameworks incorporating high-spin Fe(II) ions were structurally characterized with fascinating 1D channels and higher thermal stability: the robust frameworks still keep intact on removing free H2O or adsorbing C2H5OH, and the luminescence of [Eu-Fe] complex displays selective detection of Mg2+.
引用
收藏
页码:3113 / 3115
页数:3
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