Development of an innovative external (in air) Particle Induced Gamma-ray Emission method for rapid non-destructive determination of isotopic composition of boron in "As received" boron based ceramic neutron absorbers

Boron is an important element in nuclear reactor technology due to its high neutron absorption cross section of B-10 isotope. Isotopic composition of B (IC, B-10/B-11 atom ratio) determination in finished neutron absorbers is a necessity under chemical quality control (CQC). We report an innovative greener method for rapid and non-destructive approach of isotopic composition determination of B in "as received " boron based ceramic neutron absorbers including boron carbides and hexa-borides by external (in air) Particle Induced Gamma-ray Emission (PIGE) using 3.5 MeV proton beam. It involves irradiation of "as received " powder samples wrapped in a thin Mylar film and measurement of prompt gamma rays at 429, 718 and 2125 keV from B-10(p,alpha gamma)Be-7, B-10(p,p'gamma)B-10 and B-11(p,p'gamma)B-11, respectively, using a HPGe detector system. The method was standardized with natural and enriched B4C powders. For validation, the results of isotopic composition obtained from "as received " samples were compared with that obtained from pellet samples using both external and vacuum chamber PIGE methods. IC values obtained for natural to B-10 enriched samples (19.8-67 atom % of( 10)B) are very encouraging with 1-2% and 0.3-0.7% uncertainties from single and replicate sample experiments. The method is truly non-destructive as the samples can be returned back as such after the experiment as they are not radioactive. Compared to existing PIGE method for isotopic composition of B, the developed method keeps promise for wide applications as it is simple, sensitive and rapid and it does not require vacuum, pellet preparation with a binder, exact mass of the sample and beam current measurement.(C) 2022 Elsevier B.V. All rights reserved.