Nonionic bolaamphiphiles and gemini surfactants based on carbohydrates

被引:85
作者
Pestman, JM
Terpstra, KR
Stuart, MCA
vanDoren, HA
Brisson, A
Kellogg, RM
Engberts, JBFN
机构
[1] UNIV GRONINGEN,DEPT ORGAN & MOL INORGAN CHEM,NL-9747 AG GRONINGEN,NETHERLANDS
[2] NETHERLANDS INST CARBOHYDRATE RES,NL-9723 CC GRONINGEN,NETHERLANDS
[3] UNIV GRONINGEN,DEPT BIOPHYS CHEM,NL-9747 AG GRONINGEN,NETHERLANDS
关键词
D O I
10.1021/la970681k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nonionic bolaamphiphiles and gemini surfactants based on carbohydrates were prepared and their aggregation behavior was studied. The gemini surfactants showed interesting aggregation behavior. When the spacer length was decreased from 10 to 6 methylene groups, the vesicles formed by these surfactants become less stable and turn into threadlike micelles upon cooling, thus giving the solution a viscous and viscoelastic character. This process is reversible.
引用
收藏
页码:6857 / 6860
页数:4
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