Synthesis of biodiesel from chicken's skin waste by homogeneous transesterification

被引:18
作者
Abid, Mounir [1 ]
Touzani, A. [1 ]
Benhima, R. [2 ]
机构
[1] Mohammadia Sch Engineers, Dept Proc Engn, Ave Ibn Sina Agdal PB 765, Rabat, Morocco
[2] Moroccan Fdn Adv Sci Innovat & Res, Green Biotechnol Ctr, Rabat, Morocco
关键词
Poultry skin waste; biodiesel; esterification; transesterification; Fatty Acid Methyl Ester; ANIMAL FAT; OPTIMIZATION; PREDICTION; ESTERS; BLENDS; FUEL; LARD; OILS;
D O I
10.1080/19397038.2018.1521883
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Poultry skin waste is considered to be a promising source of biodiesel. However, this source presents an environmental threat as it is being discharged into landfills without any treatment. We studied the feasibility of biodiesel production from poultry skin waste. Two-step extraction of lipids from chicken's skin was developed and gave 97.5% yield using the optimum time and temperature. Esterification was then optimised to remove free fatty acids (FFA) where the ideal parameters were 65 degrees C during 30min with a molar ratio of methanol to oil of (1:3) and 1% of H2SO4. The third step was the transesterification which was performed using 60 degrees C and 300-600 rpm agitation for 1 h, with 1% basic catalyst and 1:3 (molar ratio) of methanol to oil. The biodiesel (FAME), was characterised using gas chromatography coupled with mass spectrometry (GC-MS) followed by chemical and physical analyses such as iodine number, acid number, flash point and cetane number. The total conversion was obtained using above conditions and most of the studied proprieties of produced biodiesel meet the EN14214 standard. This is an extremely encouraging result, offering a good source of biodiesel by valuing poultry skin waste.
引用
收藏
页码:272 / 280
页数:9
相关论文
共 35 条
[1]  
Ahmia A.C., 2014, Revue des Energies Renouvelables, V17, P335
[2]   Optimization of transesterification for methyl ester production from chicken fat [J].
Alptekin, Ertan ;
Canakci, Mustafa .
FUEL, 2011, 90 (08) :2630-2638
[3]  
[Anonymous], 2017, Renewables 2017: Global Status Report, DOI DOI 10.1016/J.RSER.2016.09.082
[4]  
[Anonymous], 2010, OECD GUID TEST CHEM
[5]  
Astbury G. R., 2008, P SAF ENV PROT, P397
[6]  
Bamgboye AI, 2008, INT AGROPHYS, V22, P21
[7]  
Bharat T., 2012, INT J ENG RES DEV, V2, P8
[8]   Beef tallow biodiesel produced in a pilot scale [J].
da Cunha, Michele Espinosa ;
Krause, Laiza Canielas ;
Aranda Moraes, Maria Silvana ;
Faccini, Candice Schmitt ;
Jacques, Rosangela Assis ;
Almeida, Suelen Rodrigues ;
Alves Rodrigues, Maria Regina ;
Caramao, Elina Bastos .
FUEL PROCESSING TECHNOLOGY, 2009, 90 (04) :570-575
[9]   Biodiesel production from vegetable oils via catalytic and non-catalytic supercritical methanol transesterification methods [J].
Demirbas, A .
PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2005, 31 (5-6) :466-487
[10]  
Dorado MP, 2002, T ASAE, V45, P525