Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones

被引：82
|
作者：
Zhang, H
Yang, CB
Li, YY
Donga, ZR
Gao, JX [1 ]
Nakamura, H
Murata, K
Ikariya, T
机构：
[1] Xiamen Univ, Dept Chem, Inst Phys Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China
[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan
[3] CREST, Meguro Ku, Tokyo 1528552, Japan
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 01期
关键词：
D O I：
10.1039/b209974h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chiral Ru cluster-based catalyst systems generated in situ from Ru-3(CO)(12) and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.
引用
收藏
页码：142 / 143
页数：2
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