Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones

被引：83

作者：

Zhang, H

Yang, CB

Li, YY

Donga, ZR

Gao, JX ^{[1
]}

Nakamura, H

Murata, K

Ikariya, T

机构：

[1] Xiamen Univ, Dept Chem, Inst Phys Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China

[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan

[3] CREST, Meguro Ku, Tokyo 1528552, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 01期

关键词：

D O I：

10.1039/b209974h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral Ru cluster-based catalyst systems generated in situ from Ru-3(CO)(12) and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.

引用

页码：142 / 143

页数：2

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