Highly efficient chiral metal cluster systems derived from Ru3(CO)12 and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones

被引：82
|
作者：
Zhang, H
Yang, CB
Li, YY
Donga, ZR
Gao, JX [1 ]
Nakamura, H
Murata, K
Ikariya, T
机构：
[1] Xiamen Univ, Dept Chem, Inst Phys Chem, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Fujian, Peoples R China
[2] Tokyo Inst Technol, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan
[3] CREST, Meguro Ku, Tokyo 1528552, Japan
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 01期
关键词：
D O I：
10.1039/b209974h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chiral Ru cluster-based catalyst systems generated in situ from Ru-3(CO)(12) and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.
引用
收藏
页码：142 / 143
页数：2
相关论文
共 50 条
  • [1] Highly efficient catalysts derived from planar chiral ferrocenes for asymmetric transfer hydrogenation of ketones
    Du, XD
    Dai, LX
    Hou, XL
    Xia, LJ
    Tang, MH
    CHINESE JOURNAL OF CHEMISTRY, 1998, 16 (01) : 90 - 93
  • [2] Highly efficient catalysts derived from planar chiral ferrocenes for asymmetric transfer hydrogenation of ketones
    杜向东
    戴立信
    侯雪龙
    夏立钧
    唐明华
    Chinese Journal of Chemistry, 1998, (01) : 90 - 93
  • [3] Highly efficient chiral PNNP ligand for asymmetric transfer hydrogenation of aromatic ketones in water
    Xing, Yan
    Chen, Jian-Shan
    Dong, Zhen-Rong
    Li, Yan-Yun
    Gao, Jing-Xing
    TETRAHEDRON LETTERS, 2006, 47 (26) : 4501 - 4503
  • [4] Highly efficient asymmetric transfer hydrogenation of ketones catalyzed by chiral 'roofed' cis-diamine-Ru(II) complex
    Matsunaga, H
    Ishizuka, T
    Kunieda, T
    TETRAHEDRON LETTERS, 2005, 46 (21) : 3645 - 3648
  • [5] A new efficient chiral iridium catalyst for asymmetric transfer hydrogenation of ketones
    Li, YY
    Zhang, H
    Chen, JS
    Liao, XL
    Dong, ZR
    Gao, JX
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 218 (02) : 153 - 156
  • [6] Asymmetric transfer hydrogenation of ketones catalyzed by chiral carbonyl iron systems
    Chen, JS
    Chen, LL
    Xing, Y
    Chen, G
    Shen, WY
    Dong, ZR
    Li, YY
    Gao, JX
    ACTA CHIMICA SINICA, 2004, 62 (18) : 1745 - 1750
  • [7] Asymmetric transfer hydrogenation of ketones using Ru(0) nanoparticles modified by Chiral Thiones
    Reshi, Noor U. Din
    Senthurpandi, Dineshchakravarthy
    Samuelson, Ashoka G.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (05)
  • [8] Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Chiral Multidentate Aminophosphine Ligands/Iron Cluster
    Wu, Fang
    Zhang, Wenjing
    An, Dongli
    Li, Yanyun
    Gao, Jingxing
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (05) : 1295 - 1299
  • [9] Novel Chiral PNNP-Ru Complexes: Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones
    Cheng Zhi-bo
    Yu Shen-luan
    Li Yan-yun
    Dong Zhen-rong
    Sun Guo-song
    Huang Ke-lin
    Gao Jing-xing
    CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2011, 27 (02) : 170 - 173
  • [10] Novel Chiral PNNP-Ru Complexes:Synthesis and Application in Asymmetric Transfer Hydrogenation of Ketones
    CHENG Zhi-bo1
    2. Guangxi Research Institute of Chemical Industry
    ChemicalResearchinChineseUniversities, 2011, 27 (02) : 170 - 173
12345