Measuring Ultrafast Spectral Diffusion and Correlation Dynamics by Two-Dimensional Electronic Spectroscopy

被引：12

作者：

Do, Thanh Nhut ^{[1
]}

Khyasudeen, M. Faisal ^{[1
,2
]}

Nowakowski, Pawel J. ^{[1
]}

Zhang, Zhengyang ^{[1
]}

Tan, Howe-Siang ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Phys & Math Sci, Disiv Chem & Biol Chem, 21 Nanyang Link, Singapore 637371, Singapore

[2] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 22期

关键词：

CdSe nanomaterials; Chlorophyll; Nonlinear Optical Spectroscopy; Spectral Diffusion; Ultrafast Spectroscopy; CHLOROPHYLL-A; ENERGY-TRANSFER; PHOTON-ECHO; SOLVATION; SIMULATION; COHERENCE; PHASE; WATER;

D O I：

10.1002/asia.201900994

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The frequency fluctuation correlation function (FFCF) measures the spectral diffusion of a state's transition while the frequency fluctuation cross-correlation function (FXCF) measures the correlation dynamics between the transitions of two separate states. These quantities contain a wealth of information on how the chromophores or excitonic states interact and couple with its environment and with each other. We summarize the experimental implementations and theoretical considerations of using two-dimensional electronic spectroscopy to characterize FFCFs and FXCFs. Applications can be found in systems such as the chlorophyll pigment molecules in light-harvesting complexes and CdSe nanomaterials.

引用

页码：3992 / 4000

页数：9

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[11] Correlated vibrational dynamics revealed by two-dimensional infrared spectroscopy -: art. no. 237401 [J].