Synthesis of nitrile-terminated potential molecular electronic devices

被引：39

作者：

Dirk, SM

Tour, JM

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Ctr Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

TETRAHEDRON | 2003年 / 59卷 / 03期

关键词：

alligator clip; nitroaniline; oligo(phenylene ethynylene);

D O I：

10.1016/S0040-4020(02)01527-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several potential molecular devices have been synthesized consisting of oligo(phenylene ethynylene) (OPE) backbones containing a terminal nitrile group alligator clip as a means of attachment to a metal surface. The synthesis of four new nitrile-containing OPEs is discussed, including an improved synthesis of an intermediate used in our prior production of OPEs containing acetate-protected thiol alligator clips. (C) 2003 Elsevier Science Ltd. All rights reserved.

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收藏

页码：287 / 293

页数：7

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