Chemical vapor transport of solid solutions.: 13.: The chemical vapor transport of mixed crystals in the system ZnS/Zn3P2

被引：8

作者：

Locmelis, S ^{[1
]}

Binnewies, M ^{[1
]}

机构：

[1] Leibniz Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 8-9期

关键词：

CVT-reaction; Zn3P2; ZnP2; mixed crystals;

D O I：

10.1002/zaac.200400100

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Heating the two solids ZnS and Zn3P2 and iodine in a temperature gradient (e. g. 1000 900 'Q the mixed phases ZnS: P (0,7%) (ZnS1-xP0,67x, x = 0... 0,019) and Zn3P2:S (1,2%) (Zn3P2-xS1,5x, x = 0... 0,005) are formed at 900degrees. Lattice parameters of Zn3P2 decrease if phophide ions are substituted by sulphide ions. Lattice parameters of ZnS increase if sulphide ions are substituted by phosphide ions. The solid/gas reactions are discussed.

引用

页码：1301 / 1307

页数：7

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