Synthesis and characterization of functionalized crosslinkable poly(ε-caprolactone)

被引：15

作者：

Laurienzo, Paola ^{[1
]}

Malinconico, Mario ^{[1
]}

Mattia, Giuditta ^{[1
]}

Romano, Gennaro ^{[1
]}

机构：

[1] CNR, ICTP, I-80078 Naples, Italy

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2006年 / 207卷 / 20期

关键词：

biopolymers; crosslinking; functionalization of polymers; mechanical properties; poly(epsilon-caprolactone);

D O I：

10.1002/macp.200600262

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new and rather simple method to obtain randomly crosslinked PCL is reported. PCL was previously functionalized through radical grafting of MA and GMA in the melt, using a Brabender-like apparatus. GMA was added I in order to obtain higher grafting efficiency. The structure of PCL-g-MAGMA was elucidated by H-1 NMR spectroscopy, and the content of grafted MA was determined by Fr-IR spectroscopy. PCL-g-MAGMA was successively crosslinked through reaction with HMDI. The degree of crosslinking was determined by solvent extractions with chloroform. Thermal and dynamic mechanical analysis and tensile tests were performed on plain PCL, on PCL-g-MAGMA and on crosslinked PCL samples.

引用

页码：1861 / 1869

页数：9

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