Ion-pair formation in electron recombination with H3+

被引：5
|
作者：
Larson, Asa [1 ]
Roos, Johanna
Orel, Ann E.
机构：
[1] Royal Inst Technol, Dept Theoret Chem, Sch Biotechnol, S-10691 Stockholm, Sweden
[2] Univ Calif Davis, Dept Appl Sci, Davis, CA 95616 USA
来源：
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2006年 / 364卷 / 1848期
关键词：
ion-pair state; wave packet dynamics; H-3(+);
D O I：
10.1098/rsta.2006.1884
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
The process of resonant ion-pair formation following electron collisions with H-3(+) is studied. The relevant diabatic potential energy surfaces and the electronic couplings between these surfaces are calculated. The reaction is then described using a time-dependent approach with wave packets propagating on the coupled potentials. In order to describe the reaction, it is found necessary to include at least two dimensions in the model. The effects of the Rydberg states on the cross-section for this process are discussed.
引用
收藏
页码：2999 / 3005
页数：7
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