Mesoporous MCM41-heterogenised (salen)Mn and Cu complexes as effective catalysts for oxidation of sulfides to sulfoxides -: Isolation of a stable supported Mn(V)=O complex, responsible of the catalytic activity

被引：77

作者：

Ayala, V

Corma, A

Iglesias, M

Sánchez, F

机构：

[1] CSIC, Inst Quim Organ Gen, Madrid 28006, Spain

[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[3] CSIC, Inst Ciencia Mat Madrid, Madrid 28049, Spain

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 221卷 / 1-2期

关键词：

immobilised salen; heterogenisation; sulfide oxidation; manganese; copper;

D O I：

10.1016/j.molcata.2004.07.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chiral salen manganese and copper complexes immobilised on mesoporous silica supports (silica, MCM-41) have been investigated as catalysts in the sulfide to sulfoxide oxidation; the supported catalysts are highly suited to reactions leading to high yields and high sulfoxide/sulfone selectivity while moderate asymmetric induction (up to 30%) was observed. The presence of stable manganyl [Mn(V)=O] complexes into support channels have been established, being responsible for catalytic activity. The recovery and reusability of heterogenised Mn- and Cu-catalysts have been studied. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：201 / 208

页数：8

共 47 条

[1] New Mn(II) and Cu(II) chiral C2-multidentate complexes immobilised in zeolites (USY, MCM41) -: Reusable catalysts for selective oxidation reactions
Alcón, MJ
Corma, A
Iglesias, M
Sánchez, F
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 194 (1-2) : 137 - 152
[2] Polymer-supported chiral Co(salen) complexes: Synthetic applications and mechanistic investigations in the hydrolytic kinetic resolution of terminal epoxides
Annis, DA
Jacobsen, EN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) : 4147 - 4154
[3] [Anonymous], 2001, FINE CHEM HETEROGENE
[4] Activities and stabilities of heterogeneous catalysts in selective liquid phase oxidations: recent developments
Arends, IWCE
Sheldon, RA
[J]. APPLIED CATALYSIS A-GENERAL, 2001, 212 (1-2) : 175 - 187
[5] Hybrid organic -: inorganic catalysts:: a cooperative effect between support, and palladium and nickel salen complexes on catalytic hydrogenation of imines
Ayala, V
Corma, A
Iglesias, M
Rincón, JA
Sánchez, F
[J]. JOURNAL OF CATALYSIS, 2004, 224 (01) : 170 - 177
[6] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
BECK, JS
VARTULI, JC
ROTH, WJ
LEONOWICZ, ME
KRESGE, CT
SCHMITT, KD
CHU, CTW
OLSON, DH
SHEPPARD, EW
MCCULLEN, SB
HIGGINS, JB
SCHLENKER, JL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
[7] Bhaduri S., 2000, HOMOGENEOUS CATALYSI
[8] Heterogeneous enantioselective epoxidation of olefins catalysed by unsymmetrical (salen) Mn(III) complexes supported on amorphous or MCM-41 silica through a new triazine-based linker
Bigi, F
Moroni, L
Maggi, R
Sartori, G
[J]. CHEMICAL COMMUNICATIONS, 2002, (07) : 716 - 717
[9] BLASER HU, 1995, CHIRAL REACTIONS IN HETEROGENEOUS CATALYSIS, P33
[10] (S)-ALPHA-METHOXYPHENYL ACETIC-ACID - A NEW NMR CHIRAL SHIFT-REAGENT FOR THE STEREOCHEMICAL ANALYSIS OF SULFOXIDES
BUIST, PH
MARECAK, D
HOLLAND, HL
BROWN, FM
[J]. TETRAHEDRON-ASYMMETRY, 1995, 6 (01) : 7 - 10

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