In situ Studies of Morphology Formation in Solution-Processed Polymer-Fullerene Blends

被引：1

作者：

Barrena, Esther ^{[1
]}

Buss, Felix ^{[2
]}

Perez-Rodriguez, Ana ^{[1
]}

Sanyal, Monamie ^{[3
]}

Schmidt-Hansberg, Benjamin ^{[2
]}

Klein, Michael F. G. ^{[4
]}

Scharfer, Philip ^{[2
]}

Schabel, Wilhelm ^{[2
]}

Lemmer, Uli ^{[4
]}

机构：

[1] Inst Ciencia Mat Barcelona ICMAB CSIC, Campus UAB, Barcelona 08193, Spain

[2] Karlsruhe Inst Technol, Thin Film Technol, Inst Thermal Proc Engn, Kaiserstr 12, D-76131 Karlsruhe, Germany

[3] Max Planck Inst Metallforsch, Heisenbergstr 3, D-70569 Stuttgart, Germany

[4] Karlsruhe Inst Technol, Light Technol Inst, Engesserstr 13, D-76131 Karlsruhe, Germany

来源：

ELEMENTARY PROCESSES IN ORGANIC PHOTOVOLTAICS | 2017年 / 272卷

关键词：

Bulk heterojunction; Crystallization; Drying kinetics; GIWAXS; P3HT; PCBM; PSBTBT; Real-time studies; Solution processing; HETEROJUNCTION SOLAR-CELLS; X-RAY; PHASE-SEPARATION; REAL-TIME; STRUCTURAL EVOLUTION; BULK HETEROJUNCTIONS; SELF-ORGANIZATION; FILMS; CRYSTALLIZATION; PERFORMANCE;

D O I：

10.1007/978-3-319-28338-8_1

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Control of the blend nanomorphology in bulk heterojunctions (BHJs) is still a challenge that demands more fundamental knowledge of the mechanism of phase separation and crystallization during solvent drying. In this review we show that in situ studies using combined laser reflectometry and grazing-incidence wide-angle X-ray scattering provide a fundamental understanding on how the nanomorphology develops dynamically during film drying. We identify influencing parameters for controlled film formation in order to obtain optimized solar cell performance. We review here our results on BHJs of poly(3-hexylthiophene)-[6,6]-phenyl-C61-butyric acid methyl ester and polyf[4,40-bis(2-ethylhexyl) dithieno(3,2-b; 20,30-d) silole]-2,6-diyl-alt-(2,1,3 benzothidiazole)-4,7-diylg with [6,6]-phenyl-C71-butyric acid methyl ester.

引用

页码：1 / 24

页数：24

共 62 条

[1] The Role of Alkane Dithiols in Controlling Polymer Crystallization in Small Band Gap Polymer:Fullerene Solar Cells [J].

Agostinelli, Tiziano ;

Ferenczi, Toby A. M. ;

Pires, E. ;

Foster, Samuel ;

Maurano, Andrea ;

Mueller, Christian ;

Ballantyne, Amy ;

Hampton, Mark ;

Lilliu, Samuele ;

Campoy-Quiles, Mariano ;

Azimi, Hamed ;

Morana, Mauro ;

Bradley, Donal D. C. ;

Durrant, James ;

Macdonald, J. Emyr ;

Stingelin, Natalie ;

Nelson, Jenny .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2011, 49 (10) :717-724

[2] Organic Ternary Solar Cells: A Review [J].

Ameri, Tayebeh ;

Khoram, Parisa ;

Min, Jie ;

Brabec, Christoph J. .

ADVANCED MATERIALS, 2013, 25 (31) :4245-4266

[3] Performance Enhancement of the P3HT/PCBM Solar Cells through NIR Sensitization Using a Small-Bandgap Polymer [J].

Ameri, Tayebeh ;

Min, Jie ;

Li, Ning ;

Machui, Florian ;

Baran, Derya ;

Forster, Michael ;

Schottler, Kristina J. ;

Dolfen, Daniel ;

Scherf, Ullrich ;

Brabec, Christoph J. .

ADVANCED ENERGY MATERIALS, 2012, 2 (10) :1198-1202

[4]

[Anonymous], PROCESS STRUCTURE PR

[5] Quantification of Thin Film Crystallographic Orientation Using X-ray Diffraction with an Area Detector [J].

Baker, Jessy L. ;

Jimison, Leslie H. ;

Mannsfeld, Stefan ;

Volkman, Steven ;

Yin, Shong ;

Subramanian, Vivek ;

Salleo, Alberto ;

Alivisatos, A. Paul ;

Toney, Michael F. .

LANGMUIR, 2010, 26 (11) :9146-9151

[6] In situ reflectance imaging of organic thin film formation from solution deposition [J].

Bergqvist, Jonas ;

Mauger, Scott A. ;

Tvingstedt, Kristofer ;

Arwin, Hans ;

Inganas, Olle .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2013, 114 :89-98

[7] Understanding the Structure and Crystallization of Regioregular Poly(3-hexylthiophene) from the Perspective of Epitaxy [J].

Brinkmann, Martin ;

Hartmann, Lucia ;

Kayunkid, Navaphun ;

Djurado, David .

P3HT REVISITED: FROM MOLECULAR SCALE TO SOLAR CELL DEVICES, 2014, 265 :83-106

[8] Low band gap polymers for organic photovoltaics [J].

Bundgaard, Eva ;

Krebs, Frederik C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (11) :954-985

[9] Morphology evolution via self-organization and lateral and vertical diffusion in polymer: fullerene solar cell blends [J].

Campoy-Quiles, Mariano ;

Ferenczi, Toby ;

Agostinelli, Tiziano ;

Etchegoin, Pablo G. ;

Kim, Youngkyoo ;

Anthopoulos, Thomas D. ;

Stavrinou, Paul N. ;

Bradley, Donal D. C. ;

Nelson, Jenny .

NATURE MATERIALS, 2008, 7 (02) :158-164

[10] Morphological study of P3HT:PCBM blend films prepared through solvent annealing for solar cell applications [J].

Chen, Fang-Chung ;

Ko, Chu-Jung ;

Wu, Jyh-Lih ;

Chen, Wei-Chi .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (12) :2426-2430

← 1 2 3 4 5 6 7 →