Magnetocaloric effect in ferrite nanoparticles

被引:139
作者
Poddar, P.
Gass, J.
Rebar, D. J.
Srinath, S.
Srikanth, H. [1 ]
Morrison, S. A.
Carpenter, E. E.
机构
[1] Univ S Florida, Dept Phys, Tampa, FL 33620 USA
[2] Virginia Commonwealth Univ, Dept Chem, Richmond, VA 23284 USA
基金
美国国家科学基金会;
关键词
magnetocaloric effect; magnetization; nanoparticles;
D O I
10.1016/j.jmmm.2006.04.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A comparative study of the magnetocaloric effect (MCE) is reported in two different types of chemically synthesized magnetic nanoparticle systems---cobalt ferrite and manganese zinc ferrite with mean size around 5 and 15 nm, respectively. While CoFe2O4 nanoparticles were synthesized using co-precipitation, the Mn0.68Zn0.25Fe2.07O4 (MZFO) nanoparticles were prepared by reverse micelle technique using AOT as surfactant. Our results indicate that the change in entropy with the change. in applied magnetic field (dS/dH) is reasonably large for this class of nanoparticles and has a wide distribution over a broad temperature range covering the region above and below the blocking temperature. The maximum entropy change is influenced by the particle size, overall distribution in anisotropy and magnetic moments. (c) 2006 Elsevier B.V.-All rights reserved.
引用
收藏
页码:227 / 231
页数:5
相关论文
共 21 条
[1]   Tunable magnetocaloric effect in ceramic perovskites [J].
Bohigas, X ;
Tejada, J ;
del Barco, E ;
Zhang, XX ;
Sales, M .
APPLIED PHYSICS LETTERS, 1998, 73 (03) :390-392
[2]   Use of multiple-edge refinement of extended x-ray absorption fine structure to determine site occupancy in mixed ferrite nanoparticles [J].
Calvin, S ;
Carpenter, EE ;
Harris, VG ;
Morrison, SA .
APPLIED PHYSICS LETTERS, 2002, 81 (20) :3828-3830
[3]   MAGNETIC MEASUREMENTS - A POWERFUL TOOL IN MAGNETIC REFRIGERATOR DESIGN [J].
FOLDEAKI, M ;
CHAHINE, R ;
BOSE, TK .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (07) :3528-3537
[4]   Large magnetic entropy change in perovskite-type manganese oxides [J].
Guo, ZB ;
Du, YW ;
Zhu, JS ;
Huang, H ;
Ding, WP ;
Feng, D .
PHYSICAL REVIEW LETTERS, 1997, 78 (06) :1142-1145
[5]   Tuning of the magnetocaloric effect in La0.67Ca0.33MnO3-δ nanoparticles synthesized by sol-gel techniques [J].
Hueso, LE ;
Sande, P ;
Miguéns, DR ;
Rivas, J ;
Rivadulla, F ;
López-Quintela, MA .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (12) :9943-9947
[6]   Influence of size distribution on the magnetocaloric effect of superparamagnetic gold-magnetite nanocomposite [J].
Kinoshita, I ;
Seino, S ;
Maruyama, H ;
Otome, Y ;
Okitsu, K ;
Nakayama, T ;
Niihara, K ;
Nakagawa, T ;
Yamamoto, TA .
JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 365 (1-2) :281-285
[7]  
Klabunde K. J., 2001, NANOSCALE MAT CHEM
[8]   Simple enhancement of the magnetocaloric effect in giant magnetocaloric materials [J].
Lewis, LH ;
Yu, MH ;
Gambino, RJ .
APPLIED PHYSICS LETTERS, 2003, 83 (03) :515-517
[9]   Synthesis of magnetic spinel ferrite CoFe2O4 nanoparticles from ferric salt and characterization of the size-dependent superparamagnetic properties [J].
Liu, C ;
Rondinone, AJ ;
Zhang, ZJ .
PURE AND APPLIED CHEMISTRY, 2000, 72 (1-2) :37-45
[10]   MAGNETOCALORIC EFFECT IN SUPERPARAMAGNETS [J].
MCMICHAEL, RD ;
SHULL, RD ;
SWARTZENDRUBER, LJ ;
BENNETT, LH ;
WATSON, RE .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1992, 111 (1-2) :29-33