Chemistry of phenylphosphonous acid fluoride: single crystal X-ray diffraction study of the acetone adduct PhP(:O)(F)C(CH3)(2)OH

被引：0

作者：

Krafczyk, R ^{[1
]}

Lambertsen, TH ^{[1
]}

Jones, PG ^{[1
]}

Schmutzler, R ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1997年 / 85卷 / 02期

关键词：

phosphonous acid fluoride; single crystal X-ray structure determination; hydrogen bonding;

D O I：

10.1016/S0022-1139(97)00062-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of phenyldifluorophosphine 1 with calcium hydroxide is an alternative route to form phenylphosphonous acid fluoride 2. The reaction of 2 with methyl ketones, MeC(:O)R, leads to addition products of type PhP(:O) (F)C(Me) (R)OH. A single crystal X-ray structure determination is described for the adduct PhP(:O) (F)C(CH3)(2)OH 8 obtained from phenylphosphonous acid fluoride 2 and acetone; hydrogen bonds of the form O-H ... O=P are observed. (C) 1997 Elsevier Science S.A.

引用

页码：135 / 139

页数：5

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