Formation of porous SnO2 microboxes via selective leaching for highly reversible lithium storage

被引：224

作者：

Zhang, Lei ^{[1
]}

Wu, Hao Bin ^{[1
]}

Liu, Bin ^{[1
]}

Lou, Xiong Wen ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, Singapore 637459, Singapore

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2014年 / 7卷 / 03期

关键词：

METAL-ORGANIC-FRAMEWORKS; SENSITIZED SOLAR-CELLS; GAS-SENSING PROPERTY; LI-ION BATTERIES; ANODE MATERIAL; HOLLOW STRUCTURES; TIN-NANOPARTICLES; AMORPHOUS OXIDE; CARBON; SPHERES;

D O I：

10.1039/c3ee43305f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous SnO2 microboxes with a high uniformity and well-defined non-spherical hollow structure are prepared via a selective leaching strategy using ZnSn(OH)(6) microboxes as the starting material. The selective removal of Zn(II) species by an acid-washing process produces pure SnO2 microboxes with a porous shell. After further wrapping with an elastic carbon matrix, the resultant SnO2@C microboxes exhibit excellent electrochemical performance as an anode material for lithium-ion batteries.

引用

页码：1013 / 1017

页数：5

共 43 条

[1] Synthesis of Uniform Hollow Oxide Nanoparticles through Nanoscale Acid Etching [J].

An, Kwangjin ;

Kwon, Soon Gu ;

Park, Mihyun ;

Na, Hyon Bin ;

Baik, Sung-Il ;

Yu, Jung Ho ;

Kim, Dokyoon ;

Son, Jae Sung ;

Kim, Young Woon ;

Song, In Chan ;

Moon, Woo Kyung ;

Park, Hyun Min ;

Hyeon, Taeghwan .

NANO LETTERS, 2008, 8 (12) :4252-4258

[2] Conversion of ternary Zn2SnO4 octahedrons into binary mesoporous SnO2 and hollow SnS2 hierarchical octahedrons by template-mediated selective complex extraction [J].

Cai, Ping ;

Ma, De-Kun ;

Liu, Quan-Cheng ;

Zhou, Shu-Mei ;

Chen, Wei ;

Huang, Shao-Ming .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (17) :5217-5223

[3] High symmetric 18-facet polyhedron nanocrystals of Cu7S4 with a hollow nanocage [J].

Cao, HL ;

Qian, XF ;

Wang, C ;

Ma, XD ;

Yin, J ;

Zhu, ZK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) :16024-16025

[4] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].

Caruso, F ;

Caruso, RA ;

Möhwald, H .

SCIENCE, 1998, 282 (5391) :1111-1114

[5] SnO2-Based Nanomaterials: Synthesis and Application in Lithium-Ion Batteries [J].

Chen, Jun Song ;

Lou, Xiong Wen .

SMALL, 2013, 9 (11) :1877-1893

[6] Functional Materials for Rechargeable Batteries [J].

Cheng, Fangyi ;

Liang, Jing ;

Tao, Zhanliang ;

Chen, Jun .

ADVANCED MATERIALS, 2011, 23 (15) :1695-1715

[7] A one-step approach towards carbon-encapsulated hollow tin nanoparticles and their application in lithium batteries [J].

Cui, Guanglei ;

Hu, Yong-Sheng ;

Zhi, Linjie ;

Wu, Dongqing ;

Lieberwirth, Ingo ;

Maier, Joachim ;

Muellen, Klaus .

SMALL, 2007, 3 (12) :2066-2069

[8] Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries [J].

Deng, Da ;

Kim, Min Gyu ;

Lee, Jim Yang ;

Cho, Jaephil .

ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (08) :818-837

[9] Nanostructured Sn-C composite as an advanced anode material in high-performance lithium-ion batteries [J].

Derrien, Gaelle ;

Hassoun, Jusef ;

Panero, Stefania ;

Scrosati, Bruno .

ADVANCED MATERIALS, 2007, 19 (17) :2336-+

[10] Nanostructured materials for electrochemical energy conversion and storage devices [J].

Guo, Yu-Guo ;

Hu, Jin-Song ;

Wan, Li-Jun .

ADVANCED MATERIALS, 2008, 20 (15) :2878-2887

← 1 2 3 4 5 →