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Morphogenesis of evaporation-induced self-assemblies of polypyrrole nanoparticles dispersed in a liquid medium
被引:23
|作者:
Jang, J
Oh, JH
机构:
[1] Seoul Natl Univ, Hyperstructured Organ Mat Res Ctr, Seoul 151742, South Korea
[2] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
来源:
关键词:
D O I:
10.1021/la049259b
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Evaporation-induced self-assemblies (EISAs) with various morphologies were selectively fabricated by drying a solution containing polypyrrole nanoparticles. The morphogenesis of EISAs was strongly dependent upon the solvent evaporation rate and the nanoparticle concentration. In the case of fast evaporation, 2-D dendrites or pseudo 1-D dendrites were observed. When the liquid medium evaporated slowly, ring and spherulitic assemblies took place. Multiple rings could be created on a substrate surface under one single drop.
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页码:8419 / 8422
页数:4
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