Preparation and characterization of chemically synthesized poly(N-methylaniline)

Poly(N-methylaniline) (PNMA), a electrically conductive derivative of polyaniline was synthesized by chemical polymerization of N-methylaniline (NmANI) using ammoniumpersulfate (APS) as an oxidizing agent and studied by electrical conductivity measurement, UV-vis and FTIR spectroscopy. The observed electrical conductivity was found to have a dependence on some synthesis parameters. The oxidant/monomer molar ratio similar to 1 and p-toluenesulfonic acid (PTSA)/monomer molar ratio similar to 4 showed higher values of electrical conductivity for the polymer. The d.c. conductivities of PTSA doped poly(N-methylaniline) have been measured in the temperature range 298-373 K. The conductivity of the samples has been observed to show an increasing trend with increasing temperature. However, on increasing temperature from 298 K to 373 K, the conductivity rise was found to be more for the samples having lower dopant/monomer ratio. The observed d.c. conductivity data was described by Mott's three-dimensional variable range hopping (VRH) model. (C) 2009 Elsevier B.V. All rights reserved.