Hydrogenation of Esters Catalyzed by Ruthenium PN3-Pincer Complexes Containing an Aminophosphine Arm

被引：72

作者：

Chen, Tao ^{[1
,2
]}

Li, Huaifeng ^{[1
]}

Qu, Shuanglin ^{[3
]}

Zheng, Bin ^{[1
]}

He, Lipeng ^{[1
]}

Lai, Zhiping ^{[1
]}

Wang, Zhi-Xiang ^{[3
]}

Huang, Kuo-Wei ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia

[2] Zhejiang Sci Tech Univ, MOE Key Lab Adv Text Mat & Mfg Technol, Natl Base Int Cooperat Sci & Technol Text & Daily, Hangzhou 310018, Zhejiang, Peoples R China

[3] Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China

来源：

ORGANOMETALLICS | 2014年 / 33卷 / 15期

关键词：

EFFICIENT HYDROGENATION; PINCER COMPLEXES; ALCOHOLS; REDUCTION; CARBONATES; ALDEHYDES; METHANOL; KETONES; CO2;

D O I：

10.1021/om500549t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrogenation of esters under mild conditions was achieved using air-stable ruthenium PN3-pincer complexes containing an aminophosphine arm. High efficiency was achieved even in the presence of water. DFT studies suggest a bimolecular proton shuttle mechanism which allows H-2 to be activated by the relatively stable catalyst with a reasonably low transition state barrier.

引用

页码：4152 / 4155

页数：4

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