Hydrogels of poly(2-hydroxyethyl methacrylate) reinforced with nanocrystalline cellulose as candidates for biomaterials

被引:14
作者
Antonio Pina-Acosta, Juan [1 ]
Zizumbo-Lopez, Arturo [1 ]
Licea-Claverie, Angel [1 ]
机构
[1] Inst Tecnol Tijuana, Ctr Grad & Invest Quim, Tijuana 22000, BC, Mexico
关键词
NANOCOMPOSITE HYDROGELS; MECHANICAL-PROPERTIES; POLYVINYL-ALCOHOL; ACID HYDROLYSIS; BEHAVIOR; COMPOSITES; DELIVERY; DRUG;
D O I
10.1002/pc.24227
中图分类号
TB33 [复合材料];
学科分类号
摘要
Nanocomposite hydrogels were prepared based on crosslinked poly(2-hydroxyethyl methacrylate) (PHEMA) as polymer matrix and nanocrystalline cellulose fibers (NCC) as nanomaterial filler. NCC fibers were obtained by acid hydrolysis of cotton and pristine PHEMA and PHEMA nanocomposite hydrogels were synthesized by photopolymerization. Physicochemical, thermal, and mechanical properties of pristine and nanocomposite hydrogels were evaluated by differential scanning calorimetry, thermogravimetric analysis, mechanical tests by submersion compression, and measurements of swelling at equilibrium. Results showed that the compressive modulus of PHEMA hydrogels increased significantly with addition of only 1wt% of NCC fibers. Furthermore, PHEMA nanocomposite hydrogels exhibit higher water swelling degree and are thermally more stable than pristine PHEMA hydrogels. POLYM. COMPOS., 39:E278-E285, 2018. (c) 2016 Society of Plastics Engineers
引用
收藏
页码:E278 / E285
页数:8
相关论文
共 29 条
[1]   Preparation and characterization of infection-resistant antibiotics-releasing hydrogels rods of poly[hydroxyethyl methacrylate-co-(poly(ethylene glycol)-methacrylate]:: Biomedical application in a novel rabbit penile prosthesis model [J].
Arica, M. Yakup ;
Tuglu, Devrim ;
Basar, M. Murad ;
Kilic, Dilek ;
Bayramoglu, Guelay ;
Batislam, Ertan .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2008, 86B (01) :18-28
[2]   Preparation By Grafting Onto, Characterization, and Properties of Thermally Responsive Polymer-Decorated Cellulose Nanocrystals [J].
Azzam, Firas ;
Heux, Laurent ;
Putaux, Jean-Luc ;
Jean, Bruno .
BIOMACROMOLECULES, 2010, 11 (12) :3652-3659
[3]   Study on the tribological properties of pHEMA hydrogels for use in artificial articular cartilage [J].
Bavaresco, V. P. ;
Zavaglia, C. A. C. ;
Reis, M. C. ;
Gomes, J. R. .
WEAR, 2008, 265 (3-4) :269-277
[4]   Dispersibility in Water of Dried Nanocrystalline Cellulose [J].
Beck, Stephanie ;
Bouchard, Jean ;
Berry, Richard .
BIOMACROMOLECULES, 2012, 13 (05) :1486-1494
[5]   Effect of reaction conditions on the properties and behavior of wood cellulose nanocrystal suspensions [J].
Beck-Candanedo, S ;
Roman, M ;
Gray, DG .
BIOMACROMOLECULES, 2005, 6 (02) :1048-1054
[6]  
Brandrup J., 1999, Polymer handbook, VII
[7]  
Chang CP, 2013, CELL CHEM TECHNOL, V47, P111
[8]   Physical and mechanical properties of polyvinyl alcohol and polypropylene composite materials reinforced with fibril aggregates isolated from regenerated cellulose fibers [J].
Cheng, Qingzheng ;
Wang, Siqun ;
Rials, Timothy G. ;
Lee, Seung-Hwan .
CELLULOSE, 2007, 14 (06) :593-602
[9]   The Potential of Cellulose Nanocrystals in Tissue Engineering Strategies [J].
Domingues, Rui M. A. ;
Gomes, Manuela E. ;
Reis, Rui L. .
BIOMACROMOLECULES, 2014, 15 (07) :2327-2346
[10]   Isolation of Thermally Stable Cellulose Nanocrystals by Phosphoric Acid Hydrolysis [J].
Espinosa, Sandra Camarero ;
Kuhnt, Tobias ;
Foster, E. Johan ;
Weder, Christoph .
BIOMACROMOLECULES, 2013, 14 (04) :1223-1230