A short and general approach to the synthesis of styryllactones:: (+)-goniodiol, its acetates and β-trifluoromethyl derivative, (+)-7-epi-goniodiol and (+)-9-deoxygoniopypyrone

被引:0
作者
Chen, J [1 ]
Lin, GQ [1 ]
Wang, ZM [1 ]
Liu, HQ [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China
关键词
(+)-goniodiol; styryllactoncs; synthesis; asymmetric dihydroxylation; cross-coupling;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
(+)-Goniodiol, its acetates and beta-trifluoromethyl derivative, (+)-7-epi-Goniodiol and (+)-9-deoxygoniopypyrone, the representatives of styryllactones have been synthesized in a short and,general way. The key steps involve the regioselective asymmetric dihydroxylation and the palladium-catalyzed cross-coupling of cyclic allylic carbonate with vinyltributylstannane.
引用
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页码:1265 / 1268
页数:4
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