Oxidative fluorination of P-H bonds in the coordination sphere of tungsten

被引：3

作者：

Bienewald, F ^{[1
]}

Huy, NHT ^{[1
]}

Mathey, F ^{[1
]}

机构：

[1] Ecole Polytech, DCPH, UMR 7653 CNRS, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 14期

关键词：

primary and secondary phosphines; fluorophosphines; phosphenium ions; pentacarbonyltungsten complexes;

D O I：

10.1016/S1387-1609(00)88464-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of triphenylcarbenium tetrafluoroborate with primary or secondary phosphine pentacarbonyltungsten complexes gives the corresponding mono or diflurorophosphine complexes. The mechanism probably involves transient phosphenium complexes. The reaction is compatible with P-O but not with P-N bonds. (C) 1999 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.

引用

页码：701 / 704

页数：4