Synthesis, Crystal Structure and Photoluminescent Properties of a New Uranium-containing Silicotungstate

被引：0

作者：

Tan, Rongxin ^{[1
]}

Cui, Shuxin ^{[1
]}

Wang, Hui ^{[1
]}

Jiang, Yaping ^{[2
]}

Song, Wenzhi ^{[2
]}

机构：

[1] Mudanjiang Normal Univ, Coll Chem & Chem Engn, Mudanjiang 157012, Peoples R China

[2] Jilin Agr Univ, China Japan Union Hosp, Dept Stomatol, Changchun 130122, Peoples R China

来源：

ADVANCED ENGINEERING MATERIALS III, PTS 1-3 | 2013年 / 750-752卷

关键词：

Polyoxometalate; Uranium; Crystal structure; Photoluminescent properties; URANYL; POLYOXOTUNGSTATES;

D O I：

10.4028/www.scientific.net/AMR.750-752.1840

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A new uranium-containing silicotungstate A-beta-Na-14[Na-2(UO2)(2)(SiW9O34)(2)]center dot 43H(2)O (1) was synthesized in an aqueous solution. The compound was characterized by elemental analysis and infrared spectra analysis. A single-crystal X-ray analysis was carried out on crystal (1) which crystallizes in triclinic system, space group p (i) over bar, with a = 13.386 angstrom, b = 13.506 angstrom, c = 16.183 angstrom, alpha = 85.337 degrees, beta = 73.608 degrees gamma = 64.833 degrees and Z = 1. Polyanion (1) consists of two A-beta-SiW9 units which sandwich two uranium and two sodium ions, leading to a Keggin-type sandwich structure. The photoluminescent spectrum of (1) shows typical emission features of uranyl compounds.

引用

页码：1840 / +

页数：2

共 15 条

[1] Structural relationships, interconversion, and optical properties of the uranyl iodates, UO2(IO3)2 and UO2(IO3)2(H2O):: A comparison of reaactions under mild and supercritical conditions
Bean, AC
Peper, SM
Albrecht-Schmitt, TE
[J]. CHEMISTRY OF MATERIALS, 2001, 13 (04) : 1266 - 1272
[2] Spectroscopic and magnetic investigation of one sandwich-type uranium(IV)-polyoxometalate with Ge(IV) as heteroatom
Craciun, C
David, L
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 : 743 - 747
[3] Critical analysis of radiochemical methodologies for the assessment of sediment pollution and dynamics in the lagoon of Venice (Italy)
Degetto, S
Cantaluppi, C
Cianchi, A
Valdarnini, F
Schintu, M
[J]. ENVIRONMENT INTERNATIONAL, 2005, 31 (07) : 1023 - 1030
[4] FEDOTOV MA, 1996, RUSS J COORD CHEM, V22, P205
[5] STUDY OF ALPHA-ENNEATUNGSTOSILICATES AND BETA-ENNEATUNGSTOSILICATES AND TUNGSTOGERMANATES
HERVE, G
TEZE, A
[J]. INORGANIC CHEMISTRY, 1977, 16 (08) : 2115 - 2117
[6] Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems
Hill, CL
[J]. CHEMICAL REVIEWS, 1998, 98 (01) : 1 - 2
[7] New heteropolytungstates incorporating dioxouranium(VI).: Derivatives of α-[SiW9O34]10-, α-[AsW9O33]9-, γ-[SiW10O36]8-, and [As4W40O140]28-
Kim, KC
Gaunt, A
Pope, MT
[J]. JOURNAL OF CLUSTER SCIENCE, 2002, 13 (03) : 423 - 436
[8] Fluorescence properties of uranyl nitrates
Leung, AF
Hayashibara, L
Spadaro, J
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1999, 60 (03) : 299 - 304
[9] Polyoxometalates: Building Blocks for Functional Nanoscale Systems
Long, De-Liang
Tsunashima, Ryo
Cronin, Leroy
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (10) : 1736 - 1758
[10] Uranyl photochemistry with alkenes: Distinguishing between H-atom abstraction and electron transfer
McCleskey, TM
Burns, CJ
Tumas, W
[J]. INORGANIC CHEMISTRY, 1999, 38 (25) : 5924 - +

← 1 2 →