Selective detection of hexachromium ions by localized surface plasmon resonance measurements using gold nanoparticles/chitosan composite interfaces

被引:36
作者
Fahnestock, Keith J. [2 ]
Manesse, Mael [1 ]
McIlwee, Holly A. [2 ]
Schauer, Caroline L. [2 ]
Boukherroub, Rabah [3 ,4 ]
Szunerits, Sabine [1 ,3 ,4 ]
机构
[1] CNRS INPG UJF, LEPMI, F-38042 St Martin Dheres, France
[2] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[3] CNRS, USR 3078, IRI, F-59652 Villeneuve Dascq, France
[4] CNRS, UMR 8520, IEMN, F-59652 Villeneuve Dascq, France
关键词
ENVIRONMENTAL WATER SAMPLES; SELF-ASSEMBLED MONOLAYER; COLORED THIN-FILMS; HEAVY-METAL IONS; HEXAVALENT CHROMIUM; CHITOSAN; ADSORPTION; SPECIATION; CYTOTOXICITY; SEPARATION;
D O I
10.1039/b817140h
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Selective removal of hexavalent chromium ions from aqueous solutions using a chitosan/gold nanoparticles composite film was demonstrated. Localized surface plasmon resonance (LSPR) was used to measure the interface stability and detect the incorporation of chromium ions over time. The effects of pH, ethylenediaminetetraacetic acid (EDTA), and various foreign ions such as trivalent chromium, sodium, calcium, phosphate, sulfate and chloride on the adsorption of hexavalent chromium were investigated.
引用
收藏
页码:881 / 886
页数:6
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