Electrochemical extraction of Ti5Si3 silicide from multicomponent Ti/Si-containing metal oxide compounds in molten salt

被引：46

作者：

Zou, Xingli ^{[1
]}

Lu, Xionggang ^{[1
]}

Zhou, Zhongfu ^{[1
,2
,3
]}

Xiao, Wei ^{[1
]}

Zhong, Qingdong ^{[1
]}

Li, Chonghe ^{[1
]}

Ding, Weizhong ^{[1
]}

机构：

[1] Shanghai Univ, Dept Mat Sci & Engn, Shanghai 200072, Peoples R China

[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England

[3] Aberystwyth Univ, Inst Math & Phys, Aberystwyth SY23 3BZ, Dyfed, Wales

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 20期

基金：

中国国家自然科学基金;

关键词：

TEMPERATURE OXIDATION BEHAVIOR; 3-PHASE INTERLINES; TITANIUM-DIOXIDE; ELECTRO-DEOXIDATION; INSULATOR COMPOUNDS; HEMATITE PARTICLES; REDUCTION; PRECURSORS; ALLOYS; CACL2;

D O I：

10.1039/c3ta15039a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ti5Si3 silicide has been extracted directly from complex multicomponent Ti/Si-containing metal oxide compounds by electro-deoxidation in molten calcium chloride using an inert solid oxide oxygen-ion-conducting membrane (SOM) based anode. Studies on the microstructure evolution and electrochemical extraction mechanism show that the formation of Ti5Si3 and the removal of impurity elements happened simultaneously during the electro-deoxidation process. It is found that the electro-deoxidation generated Ti5Si3 micro-particles typically possess a smooth surface, which could contribute to create a continuous anti-oxidation surface layer with excellent high-temperature oxidation resistance property. Consideration is also given to the parameters of electrolysis and the electrochemical characteristics including chemical and/or electrochemical reactions during the electro-deoxidation process, and then a relevant kinetic model is proposed.

引用

页码：7421 / 7430

页数：10

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