Light-Controlled Conductance Switching of Ordered Metal-Molecule-Metal Devices

被引:279
作者
van der Molen, Sense Jan [1 ,3 ]
Liao, Jianhui [1 ]
Kudernac, Tibor [2 ]
Agustsson, Jon S. [1 ]
Bernard, Laetitia [1 ]
Calame, Michel [1 ]
van Wees, Bart J.
Feringa, Ben L. [2 ]
Schoenenberger, Christian [1 ]
机构
[1] Univ Basel, Dept Phys, CH-4056 Basel, Switzerland
[2] Univ Groningen, Zernike Inst Adv Mat, Stratingh Inst, NL-9747 AG Groningen, Netherlands
[3] Leiden Univ, Kamerlingh Onnes Lab, NL-2333 CA Leiden, Netherlands
关键词
2D NANOPARTICLE ARRAYS; SINGLE-MOLECULE; DIARYLETHENES; JUNCTIONS; TRANSPORT; STATE;
D O I
10.1021/nl802487j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate reversible, light-controlled conductance switching of molecular devices based on photochromic diarylethene molecules. These devices consist of ordered, two-dimensional lattices of gold nanoparticles, in which neighboring particles are bridged by switchable molecules. We independently confirm that reversible isomerization of the diarylethenes employed is at the heart of the room-temperature conductance switching. For this, we take full advantage of the possibility to use optical spectroscopy to follow molecular switching in these samples.
引用
收藏
页码:76 / 80
页数:5
相关论文
共 36 条
  • [1] Electric field-induced isomerization of azobenzene by STM
    Alemani, Micol
    Peters, Maike V.
    Hecht, Stefan
    Rieder, Karl-Heinz
    Moresco, Francesca
    Grill, Leonhard
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (45) : 14446 - 14447
  • [2] Self-assembly of a two-dimensional superlattice of molecularly linked metal clusters
    Andres, RP
    Bielefeld, JD
    Henderson, JI
    Janes, DB
    Kolagunta, VR
    Kubiak, CP
    Mahoney, WJ
    Osifchin, RG
    [J]. SCIENCE, 1996, 273 (5282) : 1690 - 1693
  • [3] MOLECULAR RECTIFIERS
    AVIRAM, A
    RATNER, MA
    [J]. CHEMICAL PHYSICS LETTERS, 1974, 29 (02) : 277 - 283
  • [4] Spectroscopy of molecular junction networks obtained by place exchange in 2D nanoparticle arrays
    Bernard, Laetitia
    Kamdzhilov, Yavor
    Calame, Michel
    van der Molen, Sense Jan
    Liao, Jianhui
    Schoenenberger, Christian
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (50) : 18445 - 18450
  • [5] Kinetically driven self assembly of highly ordered nanoparticle monolayers
    Bigioni, TP
    Lin, XM
    Nguyen, TT
    Corwin, EI
    Witten, TA
    Jaeger, HM
    [J]. NATURE MATERIALS, 2006, 5 (04) : 265 - 270
  • [6] A molecular switch based on potential-induced changes of oxidation state
    Chen, F
    He, J
    Nuckolls, C
    Roberts, T
    Klare, JE
    Lindsay, S
    [J]. NANO LETTERS, 2005, 5 (03) : 503 - 506
  • [7] A [2]catenane-based solid state electronically reconfigurable switch
    Collier, CP
    Mattersteig, G
    Wong, EW
    Luo, Y
    Beverly, K
    Sampaio, J
    Raymo, FM
    Stoddart, JF
    Heath, JR
    [J]. SCIENCE, 2000, 289 (5482) : 1172 - 1175
  • [8] Reversible photomechanical switching of individual engineered molecules at a metallic surface
    Comstock, Matthew J.
    Levy, Niv
    Kirakosian, Armen
    Cho, Jongweon
    Lauterwasser, Frank
    Harvey, Jessica H.
    Strubbe, David A.
    Frechet, Jean M. J.
    Trauner, Dirk
    Louie, Steven G.
    Crommie, Michael F.
    [J]. PHYSICAL REVIEW LETTERS, 2007, 99 (03)
  • [9] Tuning the conductance of a molecular switch
    Del Valle, Miriam
    Gutierrez, Rafael
    Tejedor, Carlos
    Cuniberti, Gianaurelio
    [J]. NATURE NANOTECHNOLOGY, 2007, 2 (03) : 176 - 179
  • [10] Conductance switching in single molecules through conformational changes
    Donhauser, ZJ
    Mantooth, BA
    Kelly, KF
    Bumm, LA
    Monnell, JD
    Stapleton, JJ
    Price, DW
    Rawlett, AM
    Allara, DL
    Tour, JM
    Weiss, PS
    [J]. SCIENCE, 2001, 292 (5525) : 2303 - 2307