Light-Controlled Conductance Switching of Ordered Metal-Molecule-Metal Devices

被引:281
作者
van der Molen, Sense Jan [1 ,3 ]
Liao, Jianhui [1 ]
Kudernac, Tibor [2 ]
Agustsson, Jon S. [1 ]
Bernard, Laetitia [1 ]
Calame, Michel [1 ]
van Wees, Bart J.
Feringa, Ben L. [2 ]
Schoenenberger, Christian [1 ]
机构
[1] Univ Basel, Dept Phys, CH-4056 Basel, Switzerland
[2] Univ Groningen, Zernike Inst Adv Mat, Stratingh Inst, NL-9747 AG Groningen, Netherlands
[3] Leiden Univ, Kamerlingh Onnes Lab, NL-2333 CA Leiden, Netherlands
关键词
2D NANOPARTICLE ARRAYS; SINGLE-MOLECULE; DIARYLETHENES; JUNCTIONS; TRANSPORT; STATE;
D O I
10.1021/nl802487j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We demonstrate reversible, light-controlled conductance switching of molecular devices based on photochromic diarylethene molecules. These devices consist of ordered, two-dimensional lattices of gold nanoparticles, in which neighboring particles are bridged by switchable molecules. We independently confirm that reversible isomerization of the diarylethenes employed is at the heart of the room-temperature conductance switching. For this, we take full advantage of the possibility to use optical spectroscopy to follow molecular switching in these samples.
引用
收藏
页码:76 / 80
页数:5
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