The ruthenium-catalyzed addition of C-H bonds in aromatic nitriles to olefins

被引：80

作者：

Kakiuchi, F ^{[1
]}

Sonoda, M ^{[1
]}

Tsujimoto, T ^{[1
]}

Chatani, N ^{[1
]}

Murai, S ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1083

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of aromatic nitriles with triethoxyvinylsilane proceeded in the presence of a Ru(K)(2)(CO)(PPh3)(3)-catalyst to give the corresponding C-H/olefin coupling products in high yields. The nitrile group is capable of directing the ruthenium to the ortho C-H bond via pi-bonded mode.

引用

页码：1083 / 1084

页数：2

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