Highly sensitive non-enzymatic MP sensor based on electrospun copper oxide-doped zirconium oxide composite microfibers

被引:14
作者
Li, Ling [1 ]
Wang, Zhihui [1 ]
Wang, Tingting [1 ]
Gong, Jian [1 ]
Qi, Bin [1 ]
机构
[1] Northeast Normal Univ, Key Lab Polyoxometalate Sci, Minist Educ, Dept Chem, Changchun 130024, Jilin, Peoples R China
关键词
Zirconium oxide; Copper oxide; Methyl parathion; Modified electrode; Electrospinning microfibers; METHYL PARATHION; ELECTROCHEMICAL SENSOR; ORGANOPHOSPHORUS PESTICIDES; MAGNETIC NANOPARTICLES; CATALYZED HYDROLYSIS; SELECTIVE DETECTION; MESOPOROUS CARBONS; MASS-SPECTROMETRY; FACILE SYNTHESIS; GRAPHENE OXIDE;
D O I
10.1016/j.jelechem.2019.05.053
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An optimized detecting methyl parathion (MP) electrochemical sensor, fluorine tin oxide (FTO) electrodes modified by copper oxide doped zirconium oxide microfibers (CuO-ZrO2-MFs), has been successfully prepared. The CuO-ZrO2-MFs were characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and X-ray diffraction pattern (XRD). The electrochemical and electrocatalytic performances of the CuO center dot ZrO2-MFs were investigated by cyclic voltammogram (CV) and square-wave voltammogram (SWV). The CuO center dot ZrO2-MFs as non-enzymatic MP sensor shows high sensitivity of 0.002-200 ppb and low detection limit of 0.16 ppb (signal/noise radio (S/N) = 3), which are among the best values reported in literature. Additionally, excellent selectivity and reproducibility have also been observed.
引用
收藏
页数:7
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