TiO2 nanodisks designed for Li-ion batteries: a novel strategy for obtaining an ultrathin and high surface area anode material at the ice interface

被引:99
作者
Kim, Gonu [1 ]
Jo, Changshin [2 ]
Kim, Wooyul [1 ]
Chun, Jinyoung [2 ]
Yoon, Songhun [3 ]
Lee, Jinwoo [2 ]
Choi, Wonyong [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Sch Environm Sci & Engn, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol POSTECH, Dept Chem Engn, Pohang 790784, South Korea
[3] Chung Ang Univ, Dept Integrat Engn, Seoul 156756, South Korea
基金
新加坡国家研究基金会;
关键词
EXPOSED; 001; FACETS; ANATASE TIO2; LITHIUM-STORAGE; HIGH-POWER; ELECTROCHEMICAL PROPERTIES; PARTICLE-SIZE; TEMPLATE-FREE; SANDWICH-LIKE; PERFORMANCE; NANOSHEETS;
D O I
10.1039/c3ee41880d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A rapid and relatively large-scale production of ultrathin TiO2 nanodisks was achieved under mild conditions by developing a novel and simple sol-gel process occurring at the interface of an organic solvent and ice. Owing to the ultrathin structure and unusually high surface area (>400 m(2) g(-1)), the TiO2 nanodisks exhibited high reversible capacity (191.4 mA h g(-1) at 0.2 C) and excellent rate performance (58% capacity retention at 20 C) as an anode in lithium ion batteries.
引用
收藏
页码:2932 / 2938
页数:7
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